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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
Australian Journal of Chemistry

Australian Journal of Chemistry

Volume 74 Number 5 2021

CH20280Gamma Radiation-Induced Unsaturated P(VDF-CTFE) Membranes with Improved Mechanical Properties

Huazhao Wang, Yu Liu, Yaoxin Xiao, Jiafu Chen, Jinjiang Xu, Haobin Zhang, Jie Sun, Jie Li, Chunhua Zhu 0000-0001-5421-634X, Jihu Su and Feng Liu
pp. 327-334
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Fluoropolymer P(VDF-CTFE) membranes prepared by solution casting with tetrahydrofuran (THF) were radiated by a low gamma radiation dose without any other reagents, which introduced C=C bonds into the polymeric chains and resulted in a change of membrane colour and mechanical properties.

CH20299A Novel Imidazophenazine-Based Stimuli Responsive Chemosensor for Highly Selective and Sensitive Fluorescence Detection of CN

Haixiong Shi 0000-0002-8097-7932, Juanjuan Hou, Pengwei Jiang, Quanlu Yang, Qi Lin, Taibao Wei, Hong Yao, Youming Zhang and Shang Wu
pp. 335-340
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A stimuli responsive chemosensor S based on imidazophenazine was synthesised. It displayed colourimetric–fluorescence dual channel detection properties for CN based on an obvious change of colour and fluorescence. The fluorescence responding cycle could be repeated three times by the sequential addition of CN and CH3COO or CN and HSO4.

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A novel β-cyclodextrin based azo functionalized Schiff base with high aqueous solubility was synthesized. It induced high aqueous solubility in its CoII and CuII complexes. These complexes with enhanced bio-availability showed good DNA binding and DNA cleavage activities.

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Long-chained pyridinium N-chloramines were synthesised by covalent linking N-Cl unit and alkyl chain via alkylation of 3-hydroxypyridine. Compared with previous pyridinium N-chloramine that lacks intact alkyl chains, the current long-chained N-chloramines exerted distinctively elevated biocidal efficacy, probably resulting from ‘synergistic’ biocidal action between N-Cl moiety and the long-chained pyridinium moiety.

CH20330In-Cell Solid-State NMR Analysis of Membrane Proteins

Shiying Zhu 0000-0001-9906-8424, Marc-Antoine Sani 0000-0003-3284-2176 and Frances Separovic 0000-0002-6484-2763
pp. 362-363
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In-cell solid-state NMR is a potential technique to probe site-specific structural arrangements of membrane proteins in the native cellular environment. The benefits of this technique are increased sensitivity and prolonged cell lifetime, which allow the determination of complex membrane proteins within a time frame suitable for cell survival.

CH202044-(Dimethylamino)pyridine as Multivalent Catalyst in Organic Synthesis

Rosana Helena C. N. Freitas 0000-0001-5678-4535 and David Rodrigues da Rocha
pp. 364-366
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4-(Dimethylamino)pyridine (DMAP) is a common catalyst in organic synthesis, able to promote different types of reactions with an emphasis on heterocycle synthesis, multicomponent reactions (MCRs), esterification reactions, cycloadditions, and even stereoselective reactions. In this focus article, some recent and relevant uses of this catalyst have been selected to demonstrate its importance and versatility in organic chemistry.

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