A Novel Imidazophenazine-Based Stimuli Responsive Chemosensor for Highly Selective and Sensitive Fluorescence Detection of CN–
Haixiong Shi A D , Juanjuan Hou A , Pengwei Jiang B , Quanlu Yang A , Qi Lin C , Taibao Wei C , Hong Yao C , Youming Zhang C and Shang Wu BA College of Chemical Engineering, Lanzhou University of Arts and Science, Lanzhou, Gansu 730000, China.
B Key Laboratory for Utility of Environmental Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest University for Nationalities, Lanzhou, Gansu 730030, China.
C College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, China.
D Corresponding author. Email: 18091663900@163.com
Australian Journal of Chemistry 74(5) 335-340 https://doi.org/10.1071/CH20299
Submitted: 8 October 2020 Accepted: 6 December 2020 Published: 30 December 2020
Abstract
A fluorescent imidazophenazine-based derivative (S) has been successfully synthesised, and can be used as a chemsensor for relay recognition of CN– in DMSO/H2O (7 : 3, v/v) solution, which exhibited external stimuli-responsiveness. The sensor immediately responded with obvious colour changes (from red to purple) and fluorescent quenching when CN– was added to the S solution. Its detection limit for CN– is 2.16 × 10−7 M. In addition, NMR spectroscopy and density function theory calculations were also used to confirm the recognition mechanism. In particular, the fluorescence responding circle could be repeated three times by the sequential addition of CN– and CH3COO– or CN– and HSO4–. Moreover, a CN– detection test paper was prepared using S, providing a convenient method for CN– identification.
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