Australian Journal of Chemistry
Volume 74 Number 5 2021
CH20371The Future of Retrosynthesis and Synthetic Planning: Algorithmic, Humanistic or the Interplay?
Will the computer ever compete with human retrosynthetic design and the art of organic synthesis?
CH20371 Abstract | CH20371 Full Text | CH20371PDF (4.7 MB) Open Access Article
CH20280Gamma Radiation-Induced Unsaturated P(VDF-CTFE) Membranes with Improved Mechanical Properties
Fluoropolymer P(VDF-CTFE) membranes prepared by solution casting with tetrahydrofuran (THF) were radiated by a low gamma radiation dose without any other reagents, which introduced C=C bonds into the polymeric chains and resulted in a change of membrane colour and mechanical properties.
CH20299A Novel Imidazophenazine-Based Stimuli Responsive Chemosensor for Highly Selective and Sensitive Fluorescence Detection of CN–
A stimuli responsive chemosensor S based on imidazophenazine was synthesised. It displayed colourimetric–fluorescence dual channel detection properties for CN– based on an obvious change of colour and fluorescence. The fluorescence responding cycle could be repeated three times by the sequential addition of CN– and CH3COO– or CN– and HSO4–.
A novel β-cyclodextrin based azo functionalized Schiff base with high aqueous solubility was synthesized. It induced high aqueous solubility in its CoII and CuII complexes. These complexes with enhanced bio-availability showed good DNA binding and DNA cleavage activities.
Long-chained pyridinium N-chloramines were synthesised by covalent linking N-Cl unit and alkyl chain via alkylation of 3-hydroxypyridine. Compared with previous pyridinium N-chloramine that lacks intact alkyl chains, the current long-chained N-chloramines exerted distinctively elevated biocidal efficacy, probably resulting from ‘synergistic’ biocidal action between N-Cl moiety and the long-chained pyridinium moiety.
CH20285Structure and Facile Synthesis of Proton-Conducting [Fe(CN)6]3– Bridged Cd-Complex
A Cd2+ based coordination polymer material featuring 3D network was synthesized by a facile stirring method for water-mediated proton conduction.
In-cell solid-state NMR is a potential technique to probe site-specific structural arrangements of membrane proteins in the native cellular environment. The benefits of this technique are increased sensitivity and prolonged cell lifetime, which allow the determination of complex membrane proteins within a time frame suitable for cell survival.
4-(Dimethylamino)pyridine (DMAP) is a common catalyst in organic synthesis, able to promote different types of reactions with an emphasis on heterocycle synthesis, multicomponent reactions (MCRs), esterification reactions, cycloadditions, and even stereoselective reactions. In this focus article, some recent and relevant uses of this catalyst have been selected to demonstrate its importance and versatility in organic chemistry.