Register      Login
International Journal of Wildland Fire International Journal of Wildland Fire Society
Journal of the International Association of Wildland Fire
RESEARCH ARTICLE (Open Access)

Development of gas signatures of smouldering peat wildfire from emission factors

Yuqi Hu A B and Guillermo Rein https://orcid.org/0000-0001-7207-2685 B *
+ Author Affiliations
- Author Affiliations

A Sichuan Fire Research Institution, Ministry of Emergency Management of China, Chengdu, 610036, China.

B Department of Mechanical Engineering, and Leverhulme Centre for Wildfires, Environment and Society, Imperial College London, SW7 2AZ, UK.

* Correspondence to: g.rein@imperial.ac.uk

International Journal of Wildland Fire 31(11) 1014-1032 https://doi.org/10.1071/WF21093
Submitted: 21 July 2021  Accepted: 23 September 2022   Published: 9 November 2022

© 2022 The Author(s) (or their employer(s)). Published by CSIRO Publishing on behalf of IAWF. This is an open access article distributed under the Creative Commons Attribution 4.0 International License (CC BY).

Abstract

Smouldering peat fires are responsible for regional haze episodes and cause environmental, social and health crises. Owing to the unique burning characteristics of smouldering peat, identifying and detecting this kind of fire remains a challenge. This work explores smouldering peat gas signatures using emission factor (EF) data from literature. Systematic comparisons and statistical analyses were carried out to investigate 28 forms of EF combinations created from the four most abundant gas species: carbon dioxide (CO2), methane (CH4), carbon monoxide (CO) and ammonia, from smouldering peat, flaming savanna and grassland, agricultural residue and forest fires. Among the candidate gas signatures, the ratio of EF(CO2) to EF(CH4) for smouldering peat showed a significant improvement with statistically different ranges of values (134.6) compared to those from flaming savanna and grassland fire (940.2), agricultural residue fire (434.4 ), forest fire (368.8) and mixed burning peat fires (207.7). Additionally, we found that EF(CO2)/EF(CH4) is independent from fuel composition and could differentiate early ignition from the subsequent spread, making it the best gas signature among those analysed, including CO/CO2 ratio and the Modified Combustion Efficiency. This work presents the first scientific endeavour developing smouldering gas signatures, contributing to the scientific understanding and remote sensing and early detection of smouldering peat wildfires.

Keywords: detection, emissions, fire, haze, mitigation, peatland, smouldering, wildfire.


References

Akagi SK, Yokelson RJ, Wiedinmyer C, Alvarado MJ, Reid JS, Karl T, Crounse JD, Wennberg PO (2011) Emission factors for open and domestic biomass burning for use in atmospheric models. Atmospheric Chemistry and Physics 11, 4039–4072.
Emission factors for open and domestic biomass burning for use in atmospheric models.Crossref | GoogleScholarGoogle Scholar |

Andreae MO (2019) Emission of trace gases and aerosols from biomass burning – an updated assessment. Atmospheric Chemistry and Physics 19, 8523–8546.
Emission of trace gases and aerosols from biomass burning – an updated assessment.Crossref | GoogleScholarGoogle Scholar |

Andreae MO, Merlet P (2001) Emission of trace gases and aerosols from biomass burning. Global Biogeochemical Cycles 15, 955–966.
Emission of trace gases and aerosols from biomass burning.Crossref | GoogleScholarGoogle Scholar |

Belyea LR, Clymo RS (2001) Feedback control of the rate of peat formation. Proceedings of the Royal Society of London. Series B: Biological Sciences 268, 1315–1321.
Feedback control of the rate of peat formation.Crossref | GoogleScholarGoogle Scholar |

Black RR, Aurell J, Holder A, George IJ, Gullett BK, Hays MD, Geron CD, Tabor D (2016) Characterization of gas and particle emissions from laboratory burns of peat. Atmospheric Environment 132, 49–57.
Characterization of gas and particle emissions from laboratory burns of peat.Crossref | GoogleScholarGoogle Scholar |

Bluvshtein N, Villacorta E, Li C, Hagen BC, Frette V, Rudich Y (2020) Early detection of smoldering in silos: organic material emissions as precursors. Fire Safety Journal 114, 103009
Early detection of smoldering in silos: organic material emissions as precursors.Crossref | GoogleScholarGoogle Scholar |

Burke C, Wich S, Kusin K, Mcaree O, Harrison M, Ripoll B, Ermiasi Y, Mulero-Pázmány M, Longmore S (2019) Thermal-drones as a safe and reliable method for detecting subterranean peat fires. Drones 3, 23
Thermal-drones as a safe and reliable method for detecting subterranean peat fires.Crossref | GoogleScholarGoogle Scholar |

Chakrabarty RK, Gyawali M, Yatavelli RLN, Pandey A, Watts AC, Knue J, Chen L-WA, Pattison RR, Tsibart A, Samburova V, Moosmüller H (2016) Brown carbon aerosols from burning of boreal peatlands: microphysical properties, emission factors, and implications for direct radiative forcing. Atmospheric Chemistry and Physics 16, 3033–3040.
Brown carbon aerosols from burning of boreal peatlands: microphysical properties, emission factors, and implications for direct radiative forcing.Crossref | GoogleScholarGoogle Scholar |

Christensen EG, Hu Y, Restuccia F, Santoso MA, Rein G (2019) Experimental Methods and Scales in Smouldering Wildfires. In ‘Fire effects on soils properties’. (Eds P Pereira, J Mataix-Solera, X Ubeda, G Rein, A Cerda) pp. 267–280. (CSIRO Publishing: Melbourne)

Christian TJ, Kleiss B, Yokelson RJ, Holzinger R, Crutzen PJ, Hao WM, Saharjo BH, Ward DE (2003) Comprehensive laboratory measurements of biomass-burning emissions: 1. Emissions from Indonesian, African, and other fuels. Journal of Geophysical Research 108, 4719
Comprehensive laboratory measurements of biomass-burning emissions: 1. Emissions from Indonesian, African, and other fuels.Crossref | GoogleScholarGoogle Scholar |

Cochrane MA (2003) Fire science for rainforests. Nature 421, 913–919.
Fire science for rainforests.Crossref | GoogleScholarGoogle Scholar |

Ellison S, Barwick VJ, Farrant T (2009) ‘Practical statistics for the analytical scientist.’ (RSC Publishing: Cambridge)
| Crossref |

Forsyth T (2014) Public concerns about transboundary haze: A comparison of Indonesia, Singapore, and Malaysia. Global Environmental Change 25, 76–86.
Public concerns about transboundary haze: A comparison of Indonesia, Singapore, and Malaysia.Crossref | GoogleScholarGoogle Scholar |

Geron C, Hays M (2013) Air emissions from organic soil burning on the coastal plain of North Carolina. Atmospheric Environment 64, 192–199.
Air emissions from organic soil burning on the coastal plain of North Carolina.Crossref | GoogleScholarGoogle Scholar |

GraphPad Software Inc. (2022) ‘GraphPad QuickCalcs.’ (GraphPad Software: San Diego, CA, USA) Available at https://www.graphpad.com/quickcalcs

Hu Y, Rein G (2022) Data Compilation of Emission Factors Supporting the Development of Gas Signatures of Smouldering Peat Fires (Version 1.0.0) [Dataset].
| Crossref |

Hu Y, Fernandez-Anez N, Smith T, Rein G (2018a) Review of emissions from smouldering peat fires and their contribution to regional haze episodes. International Journal of Wildland Fire 27, 293–312.
Review of emissions from smouldering peat fires and their contribution to regional haze episodes.Crossref | GoogleScholarGoogle Scholar |

Hu Y, Christensen EG, Restuccia F, Rein G (2018b) Transient gas and particle emissions from smouldering combustion of peat. Proceedings of the Combustion Institute 37, 4035–4042.
Transient gas and particle emissions from smouldering combustion of peat.Crossref | GoogleScholarGoogle Scholar |

Hu Y, Christensen EG, Amin HMF, Smith TEL, Rein G (2019) Experimental study of moisture content effects on the transient gas and particle emissions from peat fires. Combustion and Flame 209, 408–417.
Experimental study of moisture content effects on the transient gas and particle emissions from peat fires.Crossref | GoogleScholarGoogle Scholar |

Huijnen V, Wooster MJ, Kaiser JW, Gaveau DLA, Flemming J, Parrington M, Inness A, Murdiyarso D, Main B, van Weele M (2016) Fire carbon emissions over maritime south-east Asia in 2015 largest since 1997. Scientific Reports 6, 26886
Fire carbon emissions over maritime south-east Asia in 2015 largest since 1997.Crossref | GoogleScholarGoogle Scholar |

Kettridge N, Turetsky MR, Sherwood JH, Thompson DK, Miller CA, Benscoter BW, Flannigan MD, Wotton BM, Waddington JM (2015) Moderate drop in water table increases peatland vulnerability to post-fire regime shift. Scientific Reports 5, 8063
Moderate drop in water table increases peatland vulnerability to post-fire regime shift.Crossref | GoogleScholarGoogle Scholar |

Madsen D, Azeem HA, Sandahl M, van Hees P, Husted B (2018) Levoglucosan as a tracer for smouldering fire. Fire Technology 54, 1871–1885.
Levoglucosan as a tracer for smouldering fire.Crossref | GoogleScholarGoogle Scholar |

Nara H, Tanimoto H, Tohjima Y, Mukai H, Nojiri Y, Machida T (2017) Emission factors of CO2, CO and CH4 from Sumatran peatland fires in 2013 based on shipboard measurements. Tellus B: Chemical and Physical Meteorology 69, 1
Emission factors of CO2, CO and CH4 from Sumatran peatland fires in 2013 based on shipboard measurements.Crossref | GoogleScholarGoogle Scholar |

Page SE, Siegert F, Rieley JO, Boehm H-DV, Jaya A, Limin S (2002) The amount of carbon released from peat and forest fires in Indonesia during 1997. Nature 420, 61–65.
The amount of carbon released from peat and forest fires in Indonesia during 1997.Crossref | GoogleScholarGoogle Scholar |

Ray SK, Singh RP, Sahay N, Varma NK (2004) Assessing the status of sealed fire in underground coal mines. Journal of Scientific & Industrial Research 63, 579–591.
Assessing the status of sealed fire in underground coal mines.Crossref | GoogleScholarGoogle Scholar |

Rein G (2013) Smouldering fires and natural fuels. In ‘Fire phenomena and the Earth system: an interdisciplinary guide to fire science’. (Ed. CM Belcher) pp. 15–34. (John Wiley & Sons: Oxford)

Rein G (2016) Smouldering combustion. In ‘The SFPE handbook of fire protection engineering’. (Ed. MJ Hurley) pp. 581–603. (Springer: New York)

Rein G, Cohen S, Simeoni A (2009) Carbon emissions from smouldering peat in shallow and strong fronts. Proceedings of the Combustion Institute 32, 2489–2496.
Carbon emissions from smouldering peat in shallow and strong fronts.Crossref | GoogleScholarGoogle Scholar |

Selimovic V, Yokelson RJ, Warneke C, Roberts JM, de Gouw J, Reardon J, Griffith DWT (2018) Aerosol optical properties and trace gas emissions by PAX and OP-FTIR for laboratory-simulated western US wildfires during FIREX. Atmospheric Chemistry and Physics 18, 2929–2948.
Aerosol optical properties and trace gas emissions by PAX and OP-FTIR for laboratory-simulated western US wildfires during FIREX.Crossref | GoogleScholarGoogle Scholar |

Smith TEL, Evers S, Yule CM, Gan JY (2018) In situ tropical peatland fire emission factors and their variability, as determined by field measurements in Peninsula Malaysia. Global Biogeochemical Cycles 32, 18–31.
In situ tropical peatland fire emission factors and their variability, as determined by field measurements in Peninsula Malaysia.Crossref | GoogleScholarGoogle Scholar |

Sofan P, Bruce D, Jones E, Marsden J (2019) Detection and Validation of Tropical Peatland Flaming and Smouldering Using Landsat-8 SWIR and TIRS Bands. Remote Sensing 11, 465
Detection and Validation of Tropical Peatland Flaming and Smouldering Using Landsat-8 SWIR and TIRS Bands.Crossref | GoogleScholarGoogle Scholar |

Stockwell CE, Yokelson RJ, Kreidenweis SM, Robinson AL, DeMott PJ, Sullivan RC, Reardon J, Ryan KC, Griffith DWT, Stevens L (2014) Trace gas emissions from combustion of peat, crop residue, domestic biofuels, grasses, and other fuels: configuration and Fourier transform infrared (FTIR) component of the fourth Fire Lab at Missoula Experiment (FLAME-4). Atmospheric Chemistry and Physics 14, 9727–9754.
Trace gas emissions from combustion of peat, crop residue, domestic biofuels, grasses, and other fuels: configuration and Fourier transform infrared (FTIR) component of the fourth Fire Lab at Missoula Experiment (FLAME-4).Crossref | GoogleScholarGoogle Scholar |

Stockwell CE, Veres PR, Williams J, Yokelson RJ (2015) Characterization of biomass burning emissions from cooking fires, peat, crop residue, and other fuels with high-resolution proton-transfer-reaction time-of-flight mass spectrometry. Atmospheric Chemistry and Physics 15, 845–865.
Characterization of biomass burning emissions from cooking fires, peat, crop residue, and other fuels with high-resolution proton-transfer-reaction time-of-flight mass spectrometry.Crossref | GoogleScholarGoogle Scholar |

Stockwell CE, Jayarathne T, Cochrane MA, Ryan KC, Putra EI, Saharjo BH, Nurhayati AD, Albar I, Blake DR, Simpson IJ, Stone EA, Yokelson RJ (2016) Field measurements of trace gases and aerosols emitted by peat fires in central Kalimantan, Indonesia, during the 2015 El Niño. Atmospheric Chemistry and Physics 16, 11711–11732.
Field measurements of trace gases and aerosols emitted by peat fires in central Kalimantan, Indonesia, during the 2015 El Niño.Crossref | GoogleScholarGoogle Scholar |

Turetsky MR, Benscoter B, Page S, Rein G, van Der Werf GR, Watts A (2015) Global vulnerability of peatlands to fire and carbon loss. Nature Geoscience 8, 11–14.
Global vulnerability of peatlands to fire and carbon loss.Crossref | GoogleScholarGoogle Scholar |

Ward DE, Radke LF (1993) Emissions measurements from vegetation fires: a comparative evaluation of methods and results. In ‘Fire in the environment: the ecological, atmospheric, and climatic importance of vegetation fires’. (Eds PJ Crutzen, JG Goldammer) pp. 53–76. (John Wiley & Sons: Oxford)

Wiggins EB, Czimczik CI, Santos GM, Chen Y, Xu X, Holden SR, Randerson JT, Harvey CF, Kai FM, Yu LE (2018) Smoke radiocarbon measurements from Indonesian fires provide evidence for burning of millennia-aged peat. Proceedings of the National Academy of Sciences 115, 12419–12424.
Smoke radiocarbon measurements from Indonesian fires provide evidence for burning of millennia-aged peat.Crossref | GoogleScholarGoogle Scholar |

Wilson D, Dixon SD, Artz RRE, Smith TEL, Evans CD, Owen HJF, Archer E, Renou-Wilson F (2015) Derivation of greenhouse gas emission factors for peatlands managed for extraction in the Republic of Ireland and the United Kingdom. Biogeosciences 12, 5291–5308.
Derivation of greenhouse gas emission factors for peatlands managed for extraction in the Republic of Ireland and the United Kingdom.Crossref | GoogleScholarGoogle Scholar |

Wooster MJ, Gaveau DLA, Salim MA, Zhang T, Xu W, Green DC, Huijnen V, Murdiyarso D, Gunawan D, Borchard N, Schirrmann M, Main B, Sepriando A (2018) New tropical peatland gas and particulate emissions factors indicate 2015 Indonesian fires released far more particulate matter (but less methane) than current inventories imply. Remote Sensing 10, 495
New tropical peatland gas and particulate emissions factors indicate 2015 Indonesian fires released far more particulate matter (but less methane) than current inventories imply.Crossref | GoogleScholarGoogle Scholar |

Yokelson RJ, Susott R, Ward DE, Reardon J, Griffith DWT (1997) Emissions from smoldering combustion of biomass measured by open-path Fourier transform infrared spectroscopy. Journal of Geophysical Research 102, 18865–18877.
Emissions from smoldering combustion of biomass measured by open-path Fourier transform infrared spectroscopy.Crossref | GoogleScholarGoogle Scholar |

Yu ZC (2012) Northern peatland carbon stocks and dynamics: a review. Biogeosciences 9, 4071–4085.
Northern peatland carbon stocks and dynamics: a review.Crossref | GoogleScholarGoogle Scholar |