The bimetallic metal–organic frameworks of FeNi-BDC and FeNi-BDC-NH2 (BDC, 1,4-benzenedicarboxylate) with similar Fe/Ni molar ratio, crystal structure, porosity and thermal stability were synthesized by a solvothermal method. FeNi-BDC-NH2 demonstrated superior NO adsorption performance and high adsorption selectivity, indicating that the introduction of NH2 on the ligand can improve the adsorption capacity and selectivity of the material for NO, which also provides a new strategy for adsorption and separation of NO in a flue gas environment. (Image credit: Li Hao.)
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Australian Journal of Chemistry
Volume 77 Number 8 2024