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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
Australian Journal of Chemistry

Australian Journal of Chemistry

Volume 75 Number 5 2022

CH21264Exploring the electronic properties of N-doped graphene on graphitic and pyridinic models and its interaction with K+ ions using the DFTB method

Yuniawan Hidayat 0000-0003-2258-5292, Fitria Rahmawati, Khoirina Dwi Nugrahaningtyas, Abdurro’Uf Althof Abiyyi, Mohamad Zola Erlangga and Nourma Pujiastuti
pp. 325-330
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The band structure of graphene, N-graphitic graphene, defect-graphene, and N-pyridinic graphene reveals the band opening features that influence adsorption interactions with K+ ions. The ease with which K+ ions interact on the graphene surface is facilitated by a larger bandgap energy. The bandgap energies of vacantcy-containing graphene and N-pyridine-doped graphene are larger, leading to greater K+ ion interactions. In the pyridine arrangement, the presence of N doping degrades graphene symmetry, changes Fermi levels and increases the bandgap. The greater the bandgap, the stronger the interaction of graphene with K+ ions. The interaction between K+ ions and N-pyridine-doped graphene, however, results in an energy that is too high in this approach.

CH22046Simple and modestly scalable synthesis of iso-Cyrene from levoglucosenone and its comparison to the bio-derived and polar aprotic solvent Cyrene®

Xin Liu, Brett Pollard, Martin G. Banwell 0000-0002-0582-475X, Li-Juan Yu, Michelle L. Coote, Michael G. Gardiner, Barbara M. A. van Vugt-Lussenburg, Bart van der Burg, Fabien L. Grasset, Elisabeth Campillo, James Sherwood, Fergal P. Byrne and Thomas J. Farmer
pp. 331-344
Graphical Abstract Image

Cyrene® (2), a commercially available solvent, is obtained by hydrogenation of levoglucosenone (LGO, 1), itself the product of pyrolysis of acid-treated cellulose. iso-Cyrene (4) has now been prepared from iso-LGO (3) and shown to display certain complementary solvent properties.

CH22001Fluorescent assay for carbendazim determination using aptamer and SYBR Green I

Yuzheng Shi, Xicheng Xie, Lumei Wang 0000-0002-2543-9779, Linzheng Wang, Lingyun Li, Zhiyu Yan and Guoqing Shen
pp. 345-352
Graphical Abstract Image

This paper proposes a fluorescent aptasensor for detecting carbendazim (CBZ) based on the interaction among CBZ, CBZ-aptamer and Synergy Brands, SYBR Green I (SG-I). The results show the aptasensor has a linear range from 3.58 to 230 nM and a good limit of detection (LOD) of 3.58 nM.

Graphical Abstract Image

The solubility of CO2 in some of ionic liquids (ILs) was measured. CO2 solubility in ILs with different alkyl chain lengths in the cation increased with increasing alkyl chain length. Also, CO2 solubility increased with increasing anion basicity.

CH21285A sensitiveWS2nanosheet sensing platform based on chemiluminescence resonance energy transfer for the detection of ochratoxin A

Guoxin Qin 0000-0002-7843-2562, Qifeng Zhou, Huiling Li, Feiyan Yan, Jie He, Yuning Wei, Haijun Wang, Yongxian Chen, Shuibing Lao, Yuxia Yang, Lihong Luo and Renfu Mo
pp. 362-368
Graphical Abstract Image

We developed a new amplified chemiluminescence sensing platform based on WS2 nanosheet chemiluminescence resonance energy transfer (CRET) for light on detection of ochratoxin A (OTA). In this study, lambda exonuclease (λexo) was added to catalyse the degradation of phosphate-DNA in the dsDNA, which can then provide a stable supply of a form of the OTA aptamer-12-mer linker-DNAzyme that can easily bind to hemin and OTA.

CH21189Properties tuning of supramolecular discotics by non-mesogenic triazines and acids

Chunming He 0000-0001-5108-170X, Kunlun Wang, Yue Wang, Shengang Xu, Yingliang Liu and Shaokui Cao
pp. 369-380
Graphical Abstract Image

Hydrogen-bonded supramolecules Tx-Ay were prepared by solution blending of triazine derivatives (Tx) and aromatic acids (Ay). 1H NMR and FT-IR results showed that hydrogen-bonded supramolecules were formed in all triazine-aromatic acid groups except T3-A1. DSC and POM analysis indicated that T1-A4, T2-A4 and T4-A4 in A4 series showed columnar liquid crystal behavior in a certain temperature range, while T3-A4 was nematic liquid crystal; WAXS confirmed that T1-A1, T2-A1 and T1-A4 were room temperature columnar liquid crystals.

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