Ru/MgO-catalysed selective aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

Priya Lokhande; Paresh L. Dhepe; Karen Wilson; Adam F. Lee

doi:10.1071/CH24082

RESEARCH ARTICLE (Open Access)

Previous Next Contents Vol 77(10)

Ru/MgO-catalysed selective aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

Priya Lokhande ^A ^B ^C , Paresh L. Dhepe ^A ^B ^* , Karen Wilson ^D ^* and Adam F. Lee

^D ^*

+ Author Affiliations

- Author Affiliations

^A Catalysis and Inorganic Chemistry Division, Council of Scientific & Industrial Research–National Chemical Laboratory, Dr Homi Bhabha Road, Pune, 411008, India.

^B Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, India.

^C Catalysis, School of Science, RMIT University, Melbourne, Vic. 3001, Australia.

^D Centre for Catalysis and Clean Energy, Griffith University, Gold Coast Campus, Southport, Qld 4222, Australia.

^* Correspondence to: pl.dhepe@ncl.res.in, karen.wilson6@griffith.edu.au, adam.lee@griffith.edu.au

Handling Editor: Curt Wentrup

Australian Journal of Chemistry 77, CH24082 https://doi.org/10.1071/CH24082

Submitted: 19 June 2024 Accepted: 28 August 2024 Published online: 30 September 2024

© 2024 The Author(s) (or their employer(s)). Published by CSIRO Publishing. This is an open access article distributed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License (CC BY-NC-ND)

Abstract

Biomass valorisation through the selective oxidation of carbohydrate and lipid derivatives offers access to an array of platform chemicals through energy- and atom-efficient catalytic processes. Supported metal nanoparticles are promising catalysts for the aerobic selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA), but typically require strong liquid base to achieve high selectivity. Here, we explore the utility of MgO as a solid base support for the Ru-catalysed aerobic oxidation of HMF, obtaining 68% FDCA yield at 160°C and 1.5 MPa of O₂ using <1 mol-% metal.

Keywords: bifunctional, biomass, catalysis, MgO, monomer, oxidation, platform chemical, ruthenium.

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