A Two-Dimensional Coordination Polymer Formed from Cobalt(ii) and an Extended Dipyridyl Ligand*
Hydar A. AL-Fayaad A , Rashid G. Siddique A , Kasun S. Athukorala Arachchige A and Jack K. Clegg A B
+ Author Affiliations
- Author Affiliations
A School of Chemistry and Molecular Biosciences, The University of Queensland, St Lucia, Qld 4072, Australia.
B Corresponding author. Email: j.clegg@uq.edu.au
Australian Journal of Chemistry 73(6) 547-551 https://doi.org/10.1071/CH19468
Submitted: 25 September 2019 Accepted: 25 November 2019 Published: 17 January 2020
Abstract
The synthesis of the extended dipyridyl ligand 4,4′-(2,5-dimethyl-1,4-phenylene)dipyridine (L) in an improved yield via the palladium catalysed Suzuki coupling of 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine (1) and 1,4-dibromo-2,5-dimethylbenzene (2) is reported along with its use to form a two-dimensional coordination polymer [Co2L2(OAc)4(H2O)2]n. The coordination polymer consists of one-dimensional chains of octahedral cobalt ions bridged by acetate ligands which are connected to form two dimensional sheets with square lattice (sql) topology via the dipyridyl ligands (L). The structure contains small voids totalling ~6.6 % of the unit cell volume. The crystal structures 1, L, L·2H2O, and L·2HNO3 are also reported.
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