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RESEARCH ARTICLE
Contents Vol 72(10)

H2-Generation from Alcohols by the MOF-Based Noble Metal-Free Photocatalyst Ni/CdS/TiO2@MIL-101*

Dominic Tilgner A , Mara Klarner A , Sebastian Hammon B , Martin Friedrich A , Andreas Verch C D , Niels de Jonge C E , Stephan Kümmel B and Rhett Kempe https://orcid.org/0000-0002-9138-4155 A F
+ Author Affiliations
- Author Affiliations

A Inorganic Chemistry II, Catalyst Design, University of Bayreuth, Bayreuth 95440, Germany.

B Theoretical Physics IV, University of Bayreuth, Bayreuth 95440, Germany.

C INM – Leibniz Institute for New Materials, Saarbrücken 66123, Germany.

D Carl Zeiss AG, Oberkochen 73447, Germany.

E Department of Physics, Saarland University, Saarbrücken 66123, Germany.

F Corresponding author. Email: kempe@uni-bayreuth.de

Australian Journal of Chemistry 72(10) 842-847 https://doi.org/10.1071/CH19255
Submitted: 4 June 2019  Accepted: 22 July 2019   Published: 15 August 2019

Abstract

The synthesis of important classes of chemical compounds from alcohols helps to conserve Earth’s fossil carbon resources, since alcohols can be obtained from indigestible and abundantly available biomass. The utilisation of visible light for the activation of alcohols permits alcohol-based C–N and C–C bond formation under mild conditions inaccessible with thermally operating hydrogen liberation catalysts. Herein, we report on a noble metal-free photocatalyst able to split alcohols into hydrogen and carbonyl compounds under inert gas atmosphere without the requirement of electron donors, additives, or aqueous reaction media. The reusable photocatalyst mediates C–N multiple bond formation using the oxidation of alcohols and subsequent coupling with amines. The photocatalyst consists of a CdS/TiO2 heterojunction decorated with co-catalytic Ni nanoparticles and is prepared on size-optimised colloidal metal–organic framework (MOF) crystallites.


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