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RESEARCH ARTICLE
Contents Vol 72(10)

Halogen Functionalization of Aluminium Fumarate Metal–Organic Framework via In Situ Hydrochlorination of Acetylenedicarboxylic Acid*

Tobie J. Matemb Ma Ntep A , Wei Wu A , Hergen Breitzke B , Carsten Schlüsener A , Bastian Moll A , Laura Schmolke A , Gerd Buntkowsky https://orcid.org/0000-0003-1304-9762 B and Christoph Janiak https://orcid.org/0000-0002-6288-9605 A C
+ Author Affiliations
- Author Affiliations

A Institut für Anorganische Chemie, Heinrich-Heine-Universität Düsseldorf, D-40204 Düsseldorf, Germany.

B Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Alarich-Weiss-Straße. 4, D-64287 Darmstadt, Germany.

C Corresponding author. Email: janiak@uni-duesseldorf.de

Australian Journal of Chemistry 72(10) 835-841 https://doi.org/10.1071/CH19221
Submitted: 13 May 2019  Accepted: 9 August 2019   Published: 10 September 2019

Abstract

The successful chloro-functionalization of aluminium fumarate (MIL-53-Fum) was achieved by in situ hydrochlorination of acetylenedicarboxylic acid on reaction with aluminium chloride resulting in the formation of the aluminium chlorofumarate metal–organic framework (MIL-53-Fum-Cl = [Al(OH)(Fum-Cl)]) in a one-pot reaction. The chloro functional groups decorating the pores enhance gas (CO2, CH4, and H2) sorption capacities and affinity compared with the non-functionalized MIL-53-Fum. The functionalization also results in a 2-fold increase in the selective adsorption of CO2 over CH4 compared with MIL-53-Fum.


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