Saccharin and tert-Butyl Nitrite: Cheap and Efficient Reagents for the Synthesis of 1,2,3-Benzotriazine-4-(3H)-ones from 2-Aminobenzamides under Metal-Free Conditions
Nader Ghaffari Khaligh A B , Mohad Rafie Johan A and Juan Joon Ching A
+ Author Affiliations
- Author Affiliations
A Nanotechnology and Catalysis Research Center, 3rd Floor, Block A, Institute of Postgraduate Studies, University of Malaya, 50603 Kuala Lumpur, Malaysia.
B Corresponding author. Email: ngkhaligh@gmail.com
Australian Journal of Chemistry 71(3) 186-189 https://doi.org/10.1071/CH17590
Submitted: 15 November 2017 Accepted: 30 January 2018 Published: 14 February 2018
Abstract
A mild and eco-friendly protocol for the synthesis of 1,2,3-benzotriazine-4-(3H)-ones is described using saccharin as a cheap and efficient catalyst and tert-butyl nitrite as a diazotization reagent for the first time. The current method has advantages such as cost effectiveness, energy efficiency, and simple experimental procedure, good yield of the desired product, and metal-free and environmentally benign conditions.
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