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RESEARCH ARTICLE
Contents Vol 65(2)

Divergent Synthesis of Benzo[d]thiazoles by PIFA-Mediated Cyclization of β-Oxo Thioamides

Peng Huang A , Xiaolan Fu B , Yongjiu Liang A , Rui Zhang A and Dewen Dong A B C
+ Author Affiliations
- Author Affiliations

A Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China.

B Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China.

C Corresponding author. Email: dwdong@ciac.jl.cn

Australian Journal of Chemistry 65(2) 121-128 https://doi.org/10.1071/CH11330
Submitted: 8 August 2011  Accepted: 17 October 2011   Published: 28 November 2011

Abstract

Efficient and divergent synthesis of benzo[d]thiazoles is developed from readily available β-oxo thioamides mediated by hypervalent iodine reagent phenyliodine bis(trifluoroaceate) (PIFA) based on reaction conditions selection, which involves the formation of a radical cation and its subsequent intramolecular cyclization process.


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