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Deanna obtained her BSc in chemistry, physics and mathematics from James Cook University followed by PhD research with Em/Prof. Richard Keene which received the 2006 RACI Cornforth Medal and a 2007 IUPAC Prize for Young Chemists. Following postdoctoral work with Prof. Jeff Long at UC Berkeley (2007–2009) as the Dow Chemical Company Fellow (American-Australian Association) and an 1851 Fellow, she built her independent research exploring emergent electronic phenomena in framework materials. She has held a L’Oréal Australia for Women in Science Fellowship, ARC QEII and Future Fellowships, and was the recipient of the 2017 LeFévre Medal (Australian Academy of Science).

Pavel completed his BSc in chemistry at the University of Adelaide (2010) followed by Honours Class I (2011) and PhD research (2015) in the development of spectroelectrochemical methods for framework materials at the University of Sydney with A/Prof. Deanna D’Alessandro. Following a postdoctoral position with A/Prof. Amanda Morris at Virginia Tech in the USA in the area of electrocatalytic framework materials, he received a Japan Society for the Promotion of Science (JSPS) Fellowship at the Tokyo Institute of Technology, Japan, to work with Prof. Masaki Kawano. Pavel is currently a Specially Appointed Assistant Professor in the same department.