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RESEARCH ARTICLE
Contents Vol 73(11)

Constructing an Interpenetrated NiII-Based Coordination Polymer Based on a Flexible Dicarboxylate Ligand and an N-Donor Ligand: Preparation, Topological Diversity, and Catalytic Properties

Feng Guo https://orcid.org/0000-0002-0945-8435 A C , Changhua Su B , Yuhang Fan A and Wenbing Shi A
+ Author Affiliations
- Author Affiliations

A Chongqing Key Laboratory of Inorganic Special Functional Materials, College of Chemistry and Chemical Engineering, Yangtze Normal University, Fuling, Chongqing 408100, China.

B School of Materials Science and Engineering, Liaocheng University, Liaocheng, Shandong 252059, China.

C Corresponding author. Email: guofeng1510@yeah.net

Australian Journal of Chemistry 73(11) 1060-1064 https://doi.org/10.1071/CH19498
Submitted: 3 October 2019  Accepted: 5 February 2020   Published: 26 March 2020

Abstract

A novel coordination polymer (CP) was constructed using 1,3-bis(4-carboxyphenoxy) propane (H2bcp), 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene (bimb), and NiII ions. [Ni(bcp)(bimb)]·H2O]n (1) shows an interesting 2D + 2D → 3D inclined polyrotaxane topology. The structure was characterised by many methods. This work indicates that the flexible and neutral pyridine ligand plays a significant role in constructing CPs. Furthermore, 1 is a highly efficient catalyst for the reaction of CO2 and epoxides.


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