Investigation of CO2 Adsorption on Triethylenetetramine Modified Adsorbents of TETA(n)/Zr-TSCD
Fan-Ming Yang
A B , Min Liao A , Chang-Hua Long A , Jian-Bin Fu A and Xiao-Yan Zhu A
+ Author Affiliations
- Author Affiliations
A College of Materials and Chemical Engineering, Hunan City University, Yiyang 413000, Hunan, China.
B Corresponding author. Email: yfanming@163.com
Australian Journal of Chemistry 73(11) 1051-1059 https://doi.org/10.1071/CH19541
Submitted: 28 October 2019 Accepted: 25 January 2020 Published: 31 March 2020
Abstract
In the present study, a new type of material of Zr-TSCD was first synthesized and modified with different amounts of triethylenetetramine (TETA). The properties of the adsorbents were characterised with X-ray diffraction, UV-vis diffuse reflectance spectroscopy, FT-IR spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, N2 adsorption–desorption, energy dispersion spectrum, and thermogravimetric analysis. The results suggested that Zr-TSCD (TSCD = Na3C6H5O7·2H2O) was successfully synthesized through the coordination of Zr atoms from ZrOCl2·8H2O and O species in –COO– groups. After functionalization with TETA, the structure of Zr-TSCD was preserved and the adsorption capacity of CO2 was enhanced dramatically. At 75°C, TETA(30)/Zr-TSCD achieved a maximum absorption capacity of 175.1 mg g−1 in a stream of 10 mL min−1 CO2. The adsorption capacity ratio of CO2/N2, CO2/O2, and CO2/SO2 was 10.5, 7.4, and 1.2, respectively. In addition, the adsorption capacity of CO2 remained stable during 10 adsorption–desorption cycles.
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