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RESEARCH ARTICLE
Contents Vol 72(5)

Flexible N-Donor Ligands Direct the Structural Characteristics of CoII Complexes: Syntheses, Structures, and Magnetic Properties

Yu-Ting Yang A B , Chang-Zheng Tu A , Xiao-Lin Xu A , Li-Li Xu A , Bang-Ling Yan A and Fei-Xiang Cheng A
+ Author Affiliations
- Author Affiliations

A College of Chemistry and Environmental Science, Qujing Normal University, Qujing 655011, China.

B Corresponding author. Email: 18288438002@163.com

Australian Journal of Chemistry 72(5) 341-346 https://doi.org/10.1071/CH18459
Submitted: 18 September 2018  Accepted: 19 December 2018   Published: 29 January 2019

Abstract

Solvothermal reactions of 3,3′,5,5′-biphenyltetracarboxylic acid (H4BPTC) and cobalt(ii) ions in the presence of two different flexible N-donor ancillary ligands afford two novel coordination polymers, {[Co(BPTC)0.5(bix)]·H2O}n (1), {[Co(BPTC)0.5(bpp)]·3H2O}n (2) (bix = 1,4-bis(imidazol-1-ylmethyl)benzene; bpp = 1,3-bis(4-pyridyl)propane). Their structures have been determined by elemental analyses, IR spectra, single-crystal X-ray diffraction analyses, and powder X-ray diffraction. The pillared layered framework of 1 can be simplified to a (4,6)-connected net with a Schläfli symbol of (44·62)(44·69·82). Complex 2 manifests a bilayered structure, and can be simplified to a (4,4)-connected net with a Schläfli symbol of (55·8)(54·62). The thermal stabilities of both complexes and the magnetic behaviours of 1 are also discussed.


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