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RESEARCH ARTICLE
Contents Vol 69(6)

Metallosupramolecular Chemistry of AgI Complexes with Azobis(2-pyridine) and its Derivatives

Siji Rajan A , F. Richard Keene B and Peter J. Steel A C
+ Author Affiliations
- Author Affiliations

A Department of Chemistry, University of Canterbury, Christchurch 8140, New Zealand.

B Department of Chemistry, School of Physical Sciences, University of Adelaide, Adelaide, SA 5005, Australia.

C Corresponding author. Email: peter.steel@canterbury.ac.nz

Australian Journal of Chemistry 69(6) 612-617 https://doi.org/10.1071/CH15560
Submitted: 10 September 2015  Accepted: 6 October 2015   Published: 30 October 2015

Abstract

Reactions of three azobis(2-pyridines) with silver salts lead to 1D coordination polymers whose structures have been determined by single crystal X-ray crystallography. The azobis(2-pyridines) consistently act as di-bidentate ligands that bridge silver atoms separated by distances ranging from 5.49 to 5.82 Å. Two of the coordination polymers consist of chains in which consecutive bridging ligands are orthogonally oriented. The other polymer has a considerably more complicated structure due to the more intimate involvement of the trifluoroacetate counteranions, which also act as bridges between silver centres.


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