Axially Aligned Confinement of 1,4-Bis(triethylammoniomethyl)benzene by Two p-Sulfonatocalix[4]arenes
Irene Ling A D , Yatimah Alias A , Munirah Sufiyah Abdul Rahim A , Brian W. Skelton B , Lindsay T. Byrne B and Colin L. Raston C
+ Author Affiliations
- Author Affiliations
A Chemistry Department, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia.
B Centre for Microscopy, Characterisation and Analysis, M313, University of Western Australia, 35 Stirling Highway, Crawley, WA 6009, Australia.
C Centre for Strategic Nano-Fabrication, School of Chemistry and Biochemistry, University of Western Australia, 35 Stirling Highway, Crawley, WA 6009, Australia.
D Corresponding author. Email: ireneling@siswa.um.edu.my
Australian Journal of Chemistry 65(7) 755-762 https://doi.org/10.1071/CH11449
Submitted: 25 November 2011 Accepted: 18 January 2012 Published: 28 February 2012
Abstract
A multiple component bi-layer complex containing 1,4-bis(triethylammoniomethyl)benzene and mono-phosphonium cations, and p-sulfonatocalix[4]arene involves preferential binding of the ammonium cation in the cavities of two geometrically opposed calixarenes with the mono-phosphonium cation embedded within a bilayer of calixarenes. The complex has channels between bilayers ~14 Å in diameter which are lined with both polar sulfonate groups and the hydrophobic surface of the central part of the ammonium cation. 1H NMR and 1D-ROESY experiments establish the formation of supermolecules of the bis-triethylammonium cation and two calixarenes in solution.
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