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RESEARCH ARTICLE
Contents Vol 65(1)

Silver(i) and Lead(ii) Halide Compounds with 4-Methyl-1,2,4-triazole-3-thiol

Yu-Ling Wang A B , Yun-Liang Jiang A , Qing-Yan Liu A B , Jia-Jia Wei A and Li-Qin Li A
+ Author Affiliations
- Author Affiliations

A College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China.

B Corresponding authors. Email: qyliuchem@hotmail.com; ylwangchem@gmail.com

Australian Journal of Chemistry 65(1) 50-57 https://doi.org/10.1071/CH11261
Submitted: 24 June 2011  Accepted: 10 November 2011   Published: 5 December 2011

Abstract

Four novel silver(i) and lead(ii) halide compounds with the 4-methyl-1,2,4-triazole-3-thiol (Hmptrz) ligand, namely [Ag2(mptrz)(μ3-X)]n (X = I (1) and Br (2)) and [Pb4(μ4-O)(mptrz)4(μ2-X)2] (X = I (3) and Cl (4)), have been synthesized and characterized. The structures exhibit different dimensionality depending on the nature of the metal ions. Compounds 1 and 2 are isomorphous and have 2D layered structures based on inorganic [Ag2X2]n infinite chains (X = I and Br), in which the mptrz– ligand displays a novel pentadentate bridging coordination mode. Compounds 3 and 4 have similar structures and are composed of a discrete tetranuclear lead(ii) cluster featuring an oxygen-centred Pb4(µ4-O) tetrahedron. Compounds 1 and 2 display solid-state photoluminescent emission with the maximum at 589 and 420 nm respectively. Compounds 3 and 4 show solid-state photoluminescent emission with the maximum at 710 and 540 nm respectively. Additionally, compounds 1–4 were characterized by IR, elemental analysis, powder X-ray diffraction and thermogravimetric analysis.


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