Synthesis and Characterization of Mesoporous Tin Oxide-Functionalized Reduced Graphene Oxide Nanoplatelets for Ultrasensitive Detection of Guaiacol in Red Wines
Tian Gan A B , Zhaoxia Shi A , Kaili Wang A , Junyong Sun A , Zhen Lv A and Yanming Liu A
+ Author Affiliations
- Author Affiliations
A College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, China.
B Corresponding author. Email: gantianxynu@163.com
Australian Journal of Chemistry 69(2) 220-229 https://doi.org/10.1071/CH15163
Submitted: 6 April 2015 Accepted: 11 July 2015 Published: 5 August 2015
Abstract
This work describes for the first time the use of mesoporous tin oxide-functionalized reduced graphene oxide (SnO2-rGO) as electrode modifier in combination with differential pulse voltammetry techniques for preconcentration and detection of guaiacol in red wine samples. SnO2-rGO was prepared through in situ growth of SnO2 particles on the rGO surface using cetyltrimethylammonium bromide as the structure-directing agent. Using the best set of experimental conditions, a linear response for guaiacol in the concentration range of 0.05 to 60 μM with a limit of detection of 7.2 nM (signal-to-noise ratio = 3) was obtained. Finally, the method was successfully applied to determine guaiacol in red wine samples, and the contents closely corresponded to those obtained by the reported chromatographic method.
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