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RESEARCH ARTICLE
Contents Vol 68(1)

Metal Ion-Driven Assembly of Two New Coordination Polymers Constructed by Asymmetric Tricarboxylate and Imidazole-Containing Ligands: Syntheses, Crystal Structures, and Luminescent Properties

Wenlong Liu A , Xueying Wang B , Mengqiang Wu A and Bing Wang C D E
+ Author Affiliations
- Author Affiliations

A School of Energy Science and Engineering, University of Electronic Science and Technology of China, Chengdu, 611731, China.

B College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, China.

C Institute for Chemical Engineering Technology, Yibin University, Yibin, 644000, China.

D Innovation and Practice Base for Postdoctors, Yibin University, Yibin, 644000, China.

E Corresponding author. Email: liuwenlong6666@126.com

Australian Journal of Chemistry 68(1) 121-126 https://doi.org/10.1071/CH14127
Submitted: 10 March 2014  Accepted: 12 April 2014   Published: 18 June 2014

Abstract

Two new coordination polymers, namely, {[Cd3(bpt)2(bimb)2]·2(H2O)}n (1) and [Zn3(bpt)2(bimb)2]n (2) (bpt = biphenyl-3,4′,5-tricarboxylate, bimb = 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene), have been obtained under hydrothermal conditions. Their structures have been determined by single-crystal X-ray diffraction analysis and further characterised by elemental analysis and infrared spectroscopy. Complex 1 exhibits a trinodal (4,4,4)-connected topology with Schläfli symbol of (4.62.83)4.(64.82). Complex 2 is also a three-dimensional structure and displays a (3,4,6)-connected topology with Schläfli symbol of (4.62)2.(42.66.85.102).(64.82). It is shown that the asymmetrically tricarboxylate can bear diverse structures regulated by metal ions. The photoluminescence behaviours of compounds 1 and 2 were also discussed.


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