Construction of Lanthanide–Organic Frameworks from the Flexible Bifunctional Ligand 1,3-Bis(2-cyano-4-pyridyl)propane
Baoming Ji A D , Chunying Xu A , Leilei Liu C , Guojie Yin A B and Chenxia Du B D
+ Author Affiliations
- Author Affiliations
A College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, PR China.
B College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450052, PR China.
C College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, PR China.
D Corresponding authors. Email: lyhxxjbm@126.com; dcx@zzu.edu.cn
Australian Journal of Chemistry 67(6) 895-900 https://doi.org/10.1071/CH13630
Submitted: 19 November 2013 Accepted: 29 January 2014 Published: 6 March 2014
Abstract
The solvothermal reactions of the bifunctional flexible ligand 1,3-bis(2-cyano-4-pyridyl)propane with lanthanide salts via an in situ ligand transformation reaction afforded four novel isostructural lanthanide metal–organic frameworks, formulated as {(NH4)[Ln(bcpp)2]·2H2O}n (Ln = Eu (1), Sm (2), Nd (3), and Pr (4), H2bcpp = 1,3-bis(2-carboxyl-4-pyridyl)propane). Polymers 1–4 were characterised by elemental analyses, IR spectroscopy, and single-crystal and powder X-ray diffraction. The results reveal that the four polymers are isostructural. In the molecular structures of 1–4, the bifunctional flexible ligand bcpp2– presents two kinds of conformations, trans–gauche and trans–trans, and forms a complicated 3D architecture by sharing LnIII ions. Topology analysis shows that polymers 1–4 all have a binodal (3,5)-connected (4·6·8)(4·65·83·10) topology with alternately left- and right-handed helical chains. Moreover, polymers 1–4 show similar thermal behaviour and 1 exhibits an intense characteristic red europium emission.
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