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RESEARCH ARTICLE
Contents Vol 67(6)

Hydrothermal Synthesis, Crystal Structures, and Photoluminescent Properties of Metal–Organic Frameworks Derived from 3,5-Bis(benzimidazol-1-yl)pyridine and Dicarboxylic Acids

Jiakun Xu A B E , Xiaochun Sun C , Xingchen Yan B D , Dongmei Zhang B and Mi Sun A E
+ Author Affiliations
- Author Affiliations

A Key Laboratory of Sustainable Development of Marine Fisheries, Ministry of Agriculture, Yellow Sea Fisheries Research Institute, Chinese Academy of Fishery Sciences, Qingdao 266071, China.

B Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China.

C National Oceanographic Centre, Qingdao 266071, China.

D Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China.

E Corresponding authors. Email: chenfeng858652@163.com; hhsunmi@yeah.net

Australian Journal of Chemistry 67(6) 901-906 https://doi.org/10.1071/CH13633
Submitted: 18 November 2013  Accepted: 29 January 2014   Published: 6 March 2014

Abstract

We successfully synthesized two new metal coordination polymers [Cd3(bdc)3(L)3(H2O)3]n (1) and [Co(tda)(L)]n (2) (H2bdc = 1,2-benzenedicarboxylic acid, H2tda = 2,5-thiophendicarboxylic acid, and L = 3,5-bis(benzimidazol-1-yl)pyridine), which were then characterized by IR, and elemental, X-ray powder diffraction, and X-ray single-crystal diffraction analysis. Complex 1 possesses a uninodal three-connected hcb Shubnikov hexagonal plane net with {63} topology. Complex 2 features a three-connected topological net with {82·10} topology (so-called ‘tongue-and-groove’ structure). A typical T-shaped molecular bilayer motif, which has rarely been reported previously, was successfully constructed by strategically selecting H2tda as the second ligand. In addition, the solid-state photoluminescent spectra of 1 and 2 were measured at room temperature.


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