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Covalently Cross-Linked Ferrocenyl PAMAMOS Dendrimer Networks

Marta Herrero A , José Losada B , M. Pilar García-Armada B , Beatriz Alonso A C and Carmen M. Casado A C
+ Author Affiliations
- Author Affiliations

A Departamento de Química Inorgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco 28049-Madrid, Spain.

B Departamento de Ingeniería Química Industrial, Escuela Técnica Superior de Ingenieros Industriales, Universidad Politécnica de Madrid, 28006-Madrid, Spain.

C Corresponding authors. Email: beatriz.alonso@uam.es; carmenm.casado@uam.es

Australian Journal of Chemistry 64(2) 147-152 https://doi.org/10.1071/CH10391
Submitted: 28 October 2010  Accepted: 3 December 2010   Published: 15 February 2011

Abstract

Thin films of nanostructured organic–inorganic ferrocenyl–dendritic hybrid materials have been prepared by the sol-gel approach. The electrochemically active organometallic dendritic networks have been characterized by FT-IR and solid-state 29Si NMR spectroscopy and scanning electron microscopy. The thermal behaviour was investigated using thermogravimetric analysis and differential scanning calorimetry and the redox properties were studied by cyclic voltammetry and differential pulse voltammetry.


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