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The APPEA Journal The APPEA Journal Society
Journal of Australian Energy Producers
RESEARCH ARTICLE

Wettability measurements on two sandstones: an experimental investigation before and after CO2 flooding

Cut Aja Fauziah A D , Emad A. Al-Khdheeawi A B , Ahmed Barifcani A and Stefan Iglauer C
+ Author Affiliations
- Author Affiliations

A Western Australia School of Mines: Minerals, Energy and Chemical Engineering, Discipline of Petroleum Engineering, Curtin University, Kensington, WA 6151, Australia.

B Petroleum Technology Department, University of Technology, Baghdad, Iraq.

C School of Engineering, Edith Cowan University, Joondalup, WA 6027, Australia.

D Corresponding author. Email: cutaja.fauziah@postgrad.curtin.edu.au

The APPEA Journal 60(1) 117-123 https://doi.org/10.1071/AJ19099
Submitted: 5 December 2019  Accepted: 16 January 2020   Published: 15 May 2020

Abstract

Wettability of rock–fluid systems is an important for controlling the carbon dioxide (CO2) movement and the capacities of CO2 geological trapping mechanisms. Although contact angle measurement is considered a potentially scalable parameter for evaluation of the wettability characteristics, there are still large uncertainties associated with the contact angle measurement for CO2–brine–rock systems. Thus, this study experimentally examined the wettability, before and after flooding, of two different samples of sandstone: Berea and Bandera grey sandstones. For both samples, several sets of flooding of brine (5 wt % NaCl + 1 wt % KCl in deionised water), CO2-saturated (live) brine and supercritical CO2 were performed. The contact angle measurements were conducted for the CO2–sandstone system at two different reservoir pressures (10 and 15 MPa) and at a reservoir temperature of 323 K. The results showed that both the advancing and receding contact angles of the sandstone samples after flooding were higher than that measured before flooding (i.e. after CO2 injection the sandstones became more CO2-wet). Moreover, the Bandera grey samples had higher contact angles than Berea sandstone. Thus, we conclude that CO2 flooding altered the sandstone wettability to be more CO2-wet, and Berea sandstone had a higher CO2 storage capacity than Bandera grey sandstone.

Keywords: Bandera grey sandstone, Berea sandstone, carbon capture storage, contact angle, CO2 injection.

Cut Aja Fauziah is a PhD student in the Department of Petroleum Engineering at Curtin University, WA. She has completed a Bachelor of Science in Chemistry and a Master’s in Metallurgical Engineering. Her research interests are wettability, CO2 storage and enhanced oil recovery (EOR).

Emad Al-Khdheeawi is a PhD candidate at the Department of Petroleum Engineering, Curtin University, WA. He has BSc and MSc degrees in Petroleum Engineering. Emad’s research interests are in wettability, CO2 geo-storage, reservoir simulation, rock and fluid properties, EOR and multi-phase flow through porous media.

Ahmed Barifcani has been an Associate Professor in the Department of Petroleum Engineering, Curtin University, WA since 2006. He has BSc, MSc and PhD degrees in Chemical Engineering from the University of Birmingham UK. He is a Fellow and a Chartered Scientist of the Institution of Chemical Engineers (FIChemE & CSci). He has many publications on flow assurance, LNG EOR and CO2 capture and storage. He has over 30 years of industrial experience in operation design, engineering, construction, project management, and research and development in the fields of oil refining, gas processing, petrochemicals, flow assurance and CO2 capture.

Stefan Iglauer is a Professor in the School of Engineering at Edith Cowan University, Joondalup, Western Australia. His research interests are in CO2 geo-storage, wettability and multi-phase flow through porous rock with a particular focus on atomic to pore-scale processes. Stefan has authored more than 130 technical publications; he holds a PhD in Material Science from Oxford Brookes University (UK) and an MSc in Chemistry from the University of Paderborn (Germany).


References

Al-Khdheeawi, E. A., Vialle, S., Barifcani, A., Sarmadivaleh, M., and Iglauer, S. (2017a). Impact of reservoir wettability and heterogeneity on CO2-plume migration and trapping capacity. International Journal of Greenhouse Gas Control 58, 142–158.
Impact of reservoir wettability and heterogeneity on CO2-plume migration and trapping capacity.Crossref | GoogleScholarGoogle Scholar |

Al-Khdheeawi, E. A., Vialle, S., Barifcani, A., Sarmadivaleh, M., and Iglauer, S. (2017b). Influence of CO2-wettability on CO2 migration and trapping capacity in deep saline aquifers. Greenhouse Gases: Science and Technology 7, 328–338.
Influence of CO2-wettability on CO2 migration and trapping capacity in deep saline aquifers.Crossref | GoogleScholarGoogle Scholar |

Al-Khdheeawi, E. A., Vialle, S., Barifcani, A., Sarmadivaleh, M., and Iglauer, S. (2017c). Influence of injection well configuration and rock wettability on CO2 plume behaviour and CO2 trapping capacity in heterogeneous reservoirs. Journal of Natural Gas Science and Engineering 43, 190–206.
Influence of injection well configuration and rock wettability on CO2 plume behaviour and CO2 trapping capacity in heterogeneous reservoirs.Crossref | GoogleScholarGoogle Scholar |

Al-Khdheeawi, E. A., Vialle, S., Barifcani, A., Sarmadivaleh, M., and Iglauer, S. (2017d). Influence of rock wettability on CO2 migration and storage capacity in deep saline aquifers. Energy Procedia 114, 4357–4365.
Influence of rock wettability on CO2 migration and storage capacity in deep saline aquifers.Crossref | GoogleScholarGoogle Scholar |

Al-Khdheeawi, E. A., Vialle, S., Barifcani, A., Sarmadivaleh, M., and Iglauer, S. (2018a). Effect of wettability heterogeneity and reservoir temperature on CO2 storage efficiency in deep saline aquifers. International Journal of Greenhouse Gas Control 68, 216–229.
Effect of wettability heterogeneity and reservoir temperature on CO2 storage efficiency in deep saline aquifers.Crossref | GoogleScholarGoogle Scholar |

Al-Khdheeawi, E. A., Vialle, S., Barifcani, A., Sarmadivaleh, M., and Iglauer, S. (2018b). Impact of injected water salinity on CO2 storage efficiency in homogenous reservoirs. The APPEA Journal 58, 44–50.
Impact of injected water salinity on CO2 storage efficiency in homogenous reservoirs.Crossref | GoogleScholarGoogle Scholar |

Al-Khdheeawi, E. A., Vialle, S., Barifcani, A., Sarmadivaleh, M., Zhang, Y., and Iglauer, S. (2018c). Impact of salinity on CO2 containment security in highly heterogeneous reservoirs. Greenhouse Gases: Science and Technology 8, 93–105.
Impact of salinity on CO2 containment security in highly heterogeneous reservoirs.Crossref | GoogleScholarGoogle Scholar |

Al-Khdheeawi, E. A., Vialle, S., Barifcani, A., Sarmadivaleh, M., and Iglauer, S. (2018d). The effect of WACO2 ratio on CO2 geo-sequestration efficiency in homogeneous reservoirs. Energy Procedia 154, 100–105.
The effect of WACO2 ratio on CO2 geo-sequestration efficiency in homogeneous reservoirs.Crossref | GoogleScholarGoogle Scholar |

Al-Khdheeawi, E. A., Vialle, S., Barifcani, A., Sarmadivaleh, M., and Iglauer, S. (2018e). Enhancement of CO2 trapping efficiency in heterogeneous reservoirs by water-alternating gas injection. Greenhouse Gases: Science and Technology 8, 920–931.
Enhancement of CO2 trapping efficiency in heterogeneous reservoirs by water-alternating gas injection.Crossref | GoogleScholarGoogle Scholar |

Al-Khdheeawi, E. A., Vialle, S., Barifcani, A., Sarmadivaleh, M., and Iglauer, S. (2018f). Impact of injection scenario on CO2 leakage and CO2 trapping capacity in homogeneous reservoirs. In ‘Offshore Technology Conference Asia’. (Society of Petroleum Engineers) 10.4043/28262-MS

Al-Khdheeawi, E. A., Vialle, S., Barifcani, A., Sarmadivaleh, M., and Iglauer, S. (2019). Effect of the number of water alternating CO2 injection cycles on CO2 trapping capacity. The APPEA Journal 59, 357–363.
Effect of the number of water alternating CO2 injection cycles on CO2 trapping capacity.Crossref | GoogleScholarGoogle Scholar |

Al-Yaseri, A. Z., Lebedev, M., Barifcani, A., and Iglauer, S. (2016). Receding and advancing (CO2+ brine+ quartz) contact angles as a function of pressure, temperature, surface roughness, salt type and salinity. The Journal of Chemical Thermodynamics 93, 416–423.
Receding and advancing (CO2+ brine+ quartz) contact angles as a function of pressure, temperature, surface roughness, salt type and salinity.Crossref | GoogleScholarGoogle Scholar |

Al-Yaseri, A., Zhang, Y., Ghasemiziarani, M., Sarmadivaleh, M., Lebedev, M., Roshan, H., and Iglauer, S. (2017). Permeability evolution in sandstone due to CO2 injection. Energy & Fuels 31, 12390–12398.
Permeability evolution in sandstone due to CO2 injection.Crossref | GoogleScholarGoogle Scholar |

Arif, M., Al-Yaseri, A. Z., Barifcani, A., Lebedev, M., and Iglauer, S. (2016). Impact of pressure and temperature on CO2–brine–mica contact angles and CO2–brine interfacial tension: Implications for carbon geo-sequestration. Journal of Colloid and Interface Science 462, 208–215.
Impact of pressure and temperature on CO2–brine–mica contact angles and CO2–brine interfacial tension: Implications for carbon geo-sequestration.Crossref | GoogleScholarGoogle Scholar | 26454380PubMed |

Bachu, S., Gunter, W., and Perkins, E. (1994). Aquifer disposal of CO2: hydrodynamic and mineral trapping. Energy Conversion and Management 35, 269–279.
Aquifer disposal of CO2: hydrodynamic and mineral trapping.Crossref | GoogleScholarGoogle Scholar |

Bergaya, F., and Lagaly, G. (2013). General introduction: clays, clay minerals, and clay science. In ‘Handbook of Clay Science. Development in Clay Science, Vol. 1’. (Eds F. Bergaya, B. K. G. Theng and G. Lagaly) pp. 1–18. (Elsevier: Amsterdam.)

Brigatti, M. F., Galán, E., and Theng, B. K. G. (2013). Structure and mineralogy of clay minerals. In ‘Handbook of Clay Science. Development in Clay Science, Vol. 1’. (Eds F. Bergaya., B. K. G. Theng and G. Lagaly) pp. 19–86. (Elsevier: Amsterdam.)

Coninck, H. d., Loos, M., Metz, B., Davidson, O., and Meyer, L. (2005). ‘IPCC Special Report on Carbon Dioxide Capture and Storage.’ (Cambridge University Press: Cambridge.)

Emami-Meybodi, H., Hassanzadeh, H., Green, C. P., and Ennis-King, J. (2015). Convective dissolution of CO2 in saline aquifers: progress in modeling and experiments. International Journal of Greenhouse Gas Control 40, 238–266.
Convective dissolution of CO2 in saline aquifers: progress in modeling and experiments.Crossref | GoogleScholarGoogle Scholar |

Fauziah, C. A., Al-Khdheeawi, E. A., Barifcani, A., and Iglauer, S. (2019a). Wettability measurements of mixed clay minerals at elevated temperature and pressure: implications for CO2 geo-storage. Paper presented at the SPE Gas & Oil Technology Showcase and Conference. (Society of Petroleum Engineers.) 10.2118/198591-MS

Fauziah, C. A., Al-Yaseri, A. Z., Beloborodov, R., Siddiqui, M. A., Lebedev, M., Parsons, D. F., Roshan, H., Barifcani, A., and Iglauer, P. S. (2019b). Carbon dioxide/brine, nitrogen/brine and oil/brine wettability of montmorillonite, illite and kaolinite at elevated pressure and temperature. Energy Fuels 33, 441–448.
Carbon dioxide/brine, nitrogen/brine and oil/brine wettability of montmorillonite, illite and kaolinite at elevated pressure and temperature.Crossref | GoogleScholarGoogle Scholar |

Feng, R., Zhou, G., Sarmadivaleh, M., Rezagholilou, A., and Roshan, H. (2018). The role of ductility in hydraulic fracturing: an experimental study. In ‘52nd US Rock Mechanics/Geomechanics Symposium’. (American Rock Mechanics Association.)

Feng, R., Zhang, Y., Rezagholilou, A., Roshan, H., and Sarmadivaleh, M. (2019). Brittleness Index: from conventional to hydraulic fracturing energy model. Rock Mechanics and Rock Engineering, , .
Brittleness Index: from conventional to hydraulic fracturing energy model.Crossref | GoogleScholarGoogle Scholar |

Gaus, I. (2010). Role and impact of CO2–rock interactions during CO2 storage in sedimentary rocks. International Journal of Greenhouse Gas Control 4, 73–89.
Role and impact of CO2–rock interactions during CO2 storage in sedimentary rocks.Crossref | GoogleScholarGoogle Scholar |

Grim, R. E. (1953). ‘Clay Mineralogy.’ (McGraw-Hill Book Company, Inc.: New York.)

Hesse, M. A., and Woods, A. (2010). Buoyant dispersal of CO2 during geological storage. Geophysical Research Letters 37, L01403.
Buoyant dispersal of CO2 during geological storage.Crossref | GoogleScholarGoogle Scholar |

Iglauer, S. (2011). Dissolution trapping of carbon dioxide in reservoir formation brine – A carbon storage mechanism In ‘Mass Transfer Advanced Aspects’ (Ed. H. Nakajima) pp. 233–262. (InTechOpen.)

Iglauer, S. (2017). CO2–water–rock wettability: variability, influencing factors, and implications for CO2 geostorage. Accounts of Chemical Research 50, 1134–1142.
CO2–water–rock wettability: variability, influencing factors, and implications for CO2 geostorage.Crossref | GoogleScholarGoogle Scholar | 28406029PubMed |

Iglauer, S., Pentland, C. H., and Busch, A. (2015). CO2 wettability of seal and reservoir rocks and the implications for carbon geo‐sequestration. Water Resources Research 51, 729–774.
CO2 wettability of seal and reservoir rocks and the implications for carbon geo‐sequestration.Crossref | GoogleScholarGoogle Scholar |

Krevor, S., Blunt, M. J., Benson, S. M., Pentland, C. H., Reynolds, C., Al-Menhali, A., and Niu, B. (2015). Capillary trapping for geologic carbon dioxide storage–From pore scale physics to field scale implications. International Journal of Greenhouse Gas Control 40, 221–237.
Capillary trapping for geologic carbon dioxide storage–From pore scale physics to field scale implications.Crossref | GoogleScholarGoogle Scholar |

Lander, L. M., Siewierski, L. M., Brittain, W. J., and Vogler, E. A. (1993). A systematic comparison of contact angle methods. Langmuir 9, 2237–2239.
A systematic comparison of contact angle methods.Crossref | GoogleScholarGoogle Scholar |

Lebedev, M., Zhang, Y., Sarmadivaleh, M., Barifcani, A., Al-Khdheeawi, E. A., and Iglauer, S. (2017). Carbon geosequestration in limestone: pore-scale dissolution and geomechanical weakening. International Journal of Greenhouse Gas Control 66, 106–119.
Carbon geosequestration in limestone: pore-scale dissolution and geomechanical weakening.Crossref | GoogleScholarGoogle Scholar |

Love, J. C., Estroff, L. A., Kriebel, J. K., Nuzzo, R. G., and Whitesides, G. M. (2005). Self-assembled monolayers of thiolates on metals as a form of nanotechnology. Chemical Reviews 105, 1103–1170.
Self-assembled monolayers of thiolates on metals as a form of nanotechnology.Crossref | GoogleScholarGoogle Scholar | 15826011PubMed |

Mohamed, I. M., He, J., and Nasr-El-Din, H. A. (2012). Carbon dioxide sequestration in sandstone aquifers: how does it affect the permeability? Paper presented at the Carbon Management Technology Conference, Orlando, Florida, USA. (Society of Petroleum Engineers.) 10.7122/149958-MS

Ochi, J., and Vernoux, J.-F. (1998). Permeability decrease in sandstone reservoirs by fluid injection: hydrodynamic and chemical effects. Journal of Hydrology 208, 237–248.
Permeability decrease in sandstone reservoirs by fluid injection: hydrodynamic and chemical effects.Crossref | GoogleScholarGoogle Scholar |

Pacala, S., and Socolow, R. (2004). Stabilization wedges: solving the climate problem for the next 50 years with current technologies. Science 305, 968–972.
Stabilization wedges: solving the climate problem for the next 50 years with current technologies.Crossref | GoogleScholarGoogle Scholar | 15310891PubMed |

Pentland, C. H., El‐Maghraby, R., Iglauer, S., and Blunt, M. J. (2011). Measurements of the capillary trapping of super-critical carbon dioxide in Berea sandstone. Geophysical Research Letters 38, L06401.
Measurements of the capillary trapping of super-critical carbon dioxide in Berea sandstone.Crossref | GoogleScholarGoogle Scholar |

Raupach, M. R., Marland, G., Ciais, P., Le Quéré, C., Canadell, J. G., Klepper, G., and Field, C. B. (2007). Global and regional drivers of accelerating CO2 emissions. Proceedings of the National Academy of Sciences of the United States of America 104, 10288–10293.
Global and regional drivers of accelerating CO2 emissions.Crossref | GoogleScholarGoogle Scholar | 17519334PubMed |

Ruprecht, C., Pini, R., Falta, R., Benson, S., and Murdoch, L. (2014). Hysteretic trapping and relative permeability of CO2 in sandstone at reservoir conditions. International Journal of Greenhouse Gas Control 27, 15–27.
Hysteretic trapping and relative permeability of CO2 in sandstone at reservoir conditions.Crossref | GoogleScholarGoogle Scholar |

Saraji, S., Goual, L., Piri, M., and Plancher, H. (2013). Wettability of supercritical carbon dioxide/water/quartz systems: Simultaneous measurement of contact angle and interfacial tension at reservoir conditions. Langmuir 29, 6856–6866.
Wettability of supercritical carbon dioxide/water/quartz systems: Simultaneous measurement of contact angle and interfacial tension at reservoir conditions.Crossref | GoogleScholarGoogle Scholar | 23627310PubMed |

Sayegh, S., Krause, F., Girard, M., and DeBree, C. (1990). Rock/fluid interactions of carbonated brines in a sandstone reservoir: Pembina Cardium, Alberta, Canada. SPE Formation Evaluation 5, 399–405.
Rock/fluid interactions of carbonated brines in a sandstone reservoir: Pembina Cardium, Alberta, Canada.Crossref | GoogleScholarGoogle Scholar |

Spycher, N., Pruess, K., and Ennis-King, J. (2003). CO2-H2O mixtures in the geological sequestration of CO2. I. Assessment and calculation of mutual solubilities from 12 to 100 C and up to 600 bar. Geochimica et Cosmochimica Acta 67, 3015–3031.
CO2-H2O mixtures in the geological sequestration of CO2. I. Assessment and calculation of mutual solubilities from 12 to 100 C and up to 600 bar.Crossref | GoogleScholarGoogle Scholar |

Suekane, T., Nobuso, T., Hirai, S., and Kiyota, M. (2008). Geological storage of carbon dioxide by residual gas and solubility trapping. International Journal of Greenhouse Gas Control 2, 58–64.
Geological storage of carbon dioxide by residual gas and solubility trapping.Crossref | GoogleScholarGoogle Scholar |

Wiese, B., Nimtz, M., Klatt, M., and Kühn, M. (2010). Sensitivities of injection rates for single well CO2 injection into saline aquifers. Geochemistry 70, 165–172.
Sensitivities of injection rates for single well CO2 injection into saline aquifers.Crossref | GoogleScholarGoogle Scholar |

Xu, T., Apps, J. A., and Pruess, K. (2003). Reactive geochemical transport simulation to study mineral trapping for CO2 disposal in deep arenaceous formations. Journal of Geophysical Research. Solid Earth 108, 2071.