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Environmental problems - Chemical approaches
Environmental Chemistry

Environmental Chemistry

Volume 14 Number 7 2017


Environmental context. Lipids released from lysis of phytoplankton cells are enriched in the sea surface microlayer. Such surface-active organics can be transferred through bursting bubbles to sea-spray aerosols where they can influence atmospheric chemistry. The results presented here suggest that phospholipids combine more readily with SO42− than with Br, leading to enrichment of organic-coated sulfate salts in marine aerosols.

EN17129Isolation and purification treatments change the metal-binding properties of humic acids: effect of HF/HCl treatment

Wander G. Botero, Michael Pineau, Noémie Janot, Rute F. Domingos, José Mariano, Luciana S. Rocha, Jan E. Groenenberg, Marc F. Benedetti and José P. Pinheiro
pp. 417-424

Environmental context. Studying the mechanism of binding between metals and natural organic matter is fundamental to understanding the transport and availability of these contaminants in the environment. The influence of sample treatment on the purification of organic matter showed significant differences in the interaction with metals. The results will contribute to improved modelling of metal binding to organic matter in soils, thereby providing a basis for a more realistic risk assessment.

EN17130Impacts of elevated pCO2 on trace gas emissions in two microalgae: Phaeocystis globosa and Nitzschia closterium

Pei-Feng Li, Gui-Peng Yang, Jing Zhang, Maurice Levasseur, Chun-Ying Liu, Jing Sun and Wei Yang
pp. 425-441

Environmental context. Ocean acidification can affect marine microalgae, which can produce climate-active trace gases such as dimethylsulfide and various halocarbons. We conducted monoculture experiments simulating future ocean acidification, and showed that trace gas emissions are affected by elevated pCO2 to different degrees. The responses of trace gases to elevated pCO2 are compound- and species-specific.


Environmental context. To aid the transition to sustainable chemistry there is a need to improve the degradability of chemicals and limit the use of organic solvents. Singlet oxygen, 1O2, is involved in organic synthesis and photochemical degradation; however, information on its aqueous-phase reactivity is limited. We developed cheminformatics models for photooxidation rate constants that will enable accurate assessment of aquatic photochemistry without experimentation.

EN17138A silver fibre prepared by a facile method for solid-phase microextraction of polycyclic aromatic hydrocarbons

Yu Tian, Jie Zhou, Juanjuan Feng, Xiuqin Wang, Chuannan Luo and Min Sun
pp. 451-457

Environmental context. Polycyclic aromatic hydrocarbons are widespread environmental contaminants of human health concern because of their carcinogenicity. The compounds have low water solubility and thus their measurement in water requires an efficient preconcentration step. We report a simple method for concentrating polycyclic aromatic hydrocarbons from environmental water samples based on their absorption onto a silver fibre.

EN17073Kinetics of mercury accumulation by freshwater biofilms

Perrine Dranguet, Vera I. Slaveykova and Séverine Le Faucheur
pp. 458-467

Environmental context. Mercury (Hg) is a major environmental contaminant due to its toxicity, accumulation and biomagnification along the food chain. We demonstrate that Hg accumulation by biofilms, one possible entry point for Hg into food webs, is rapid and depends on biofilm structure and composition. These findings have important implications for the understanding of Hg bioavailability and effects towards aquatic microorganisms.

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