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Environmental Chemistry Environmental Chemistry Society
Environmental problems - Chemical approaches
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Environmental Chemistry

Environmental Chemistry

Volume 21 Number 6 2024

EN24030Diversity of ammonia sources in Tianjin: nitrogen isotope analyses and simulations of aerosol ammonium

Libin Wu 0009-0006-3898-1192, Yiwen Zhang, Yunting Xiao, Jialei Zhu, Zongbo Shi 0000-0002-7157-543X, Yuantao Wang, Hong Xu, Wei Hu, Junjun Deng, Miao Tang and Pingqing Fu

A photograph of Jingang Bridge with the Tianjin Eye behind, shrouded in air pollution.

Environmental context. Atmospheric particulate NH4+, primarily produced from the reaction of NH3 and acids, is an important component of PM2.5. In this study, nitrogen stable isotope analyses and an atmospheric chemistry model were used to estimate the contribution of major NH3 sources to particulate NH4+ in Tianjin, a megacity in North China Plain (NCP). Our research has implications for investigations of NH3 emission sources and relevant pollution control in Tianjin and NCP. Photograph by Libin Wu.

This article belongs to the collection Dedication to Roy Harrison.


Stylised picture of a factory releasing CO2 underneath a reactor schematic for the Solvay process.

Environmental context. This manuscript focuses on the introduction of the conventional and modified Solvay processes. The Solvay process is used to produce sodium carbonate and sodium bicarbonate, while also providing brine management and CO2 capture. Optimal values must be used for reactant contents, temperature, salinity of the brine and stirring rate to enhance efficiency. (Image of the schematic diagram reproduced from Mourad et al. 2021 with permission.)


Image depicting photodegradation of pesticide in aqueous environments and graph of increasing degradation with time.

Environmental context. The widespread use of pesticides leads to a large amount of residues in natural waters where photochemical degradation is the main removal process. The factors influencing the photodegradation of pyrimethanil were investigated in different aqueous matrixes, and a chlorinated product was found in saline water, indicating a higher ecological risk of residual pyrimethanil in estuarine and nearshore water than in fresh water. A better understanding of the natural degradation mechanisms for pesticides will inform their safer use in agriculture. (Image credit: Jiayun Zhao.)

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