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Environmental Chemistry Environmental Chemistry Society
Environmental problems - Chemical approaches
Table of Contents

Volume 20 Numbers 1 & 2 2023

Special Issue

Dedication to Professor Kevin Francesconi

Guest Editor:
Joerg Feldmann (University of Graz, Austria)

This Special Issue is a dedication to Professor Kevin Francesconi, father of organoarsenicals in the environment, and a previous Editor-in-Chief of this journal, Environmental Chemistry.

EN23006Determination of inorganic As, DMA and MMA in marine and terrestrial tissue samples: a consensus extraction approach

Zuzana Gajdosechova 0000-0002-6174-181X, Patricia Grinberg 0000-0002-1167-6474, Kevin Kubachka, Mesay Wolle 0000-0001-5586-6643, Andrea Raab 0000-0003-2058-0105, Joerg Feldmann 0000-0002-0524-8254, Rebecca Sim 0000-0001-7398-8062, Ásta H. Pétursdóttir 0000-0002-6739-0598, Tomáš Matoušek 0000-0002-7603-1773, Stanislav Musil 0000-0001-8003-0370, Ben Wozniak, Stephen Springer, Nausheen W. Sadiq, Hakan Gurleyuk, Calvin H. Palmer, Indumathi Pihillagawa Gedara and Zoltan Mester 0000-0002-2377-2615
pp. 5-17

Environmental context. Arsenic can be found in all environmental compartments in a large number of chemical forms of varying toxicity. We performed an inter-laboratory comparison study focusing on quantitation of some of the most toxic arsenic forms in seven different biological materials and found very good agreement among the submitted results. Certification of the studied materials will provide suitable quality control samples for environmentally relevant concentrations of arsenic in food products and biota.

EN22136Quantitative analysis of arsenic containing hydrocarbons in marine samples by GC-MS

Georg Raber 0000-0002-7674-5995, Sonja Weishaupt, Fabian Lappi, Michael Stiboller 0000-0002-2895-029X and Joerg Feldmann 0000-0002-0524-8254
pp. 18-30

Environmental context. The marine ecosystem is highly elevated in arsenic in comparison to the terrestrial environment. More than 100 different naturally occurring organoarsenic compounds have been found in different marine organisms. In order to understand how highly toxic AsHCs are formed and bioaccumulate in different marine organisms, large scale monitoring of AsHCs from a range of different laboratories is necessary. Despite their toxicity, AsHCs have not been extensively studied due in part to the lack of low-cost analytical methods and the lack of commercially available standards.

EN22071Isolation and purification of arsenolipids from natural marine sources for use in speciation and toxicological studies

Michael Stiboller 0000-0002-2895-029X, Ariane Cofré Espinoza, Sophie Scholz, Georg Raber and Tanja Schwerdtle
pp. 31-43

Environmental context. Arsenic exists in different chemical forms in our environment, among others as arsenolipids that are predominately found in appreciable quantities in various marine organisms (seafood). Their origin, biosynthetic pathway, toxicity and their potential biological role are not fully understood. We report purification strategies for environmental and human health relevant arsenolipids to broaden and support innovative arsenolipid research.

EN22098Assessment of trace element content throughout the white shrimp (Litopenaeus vannamei) farming cycle

Wladiana O. Matos 0000-0002-7514-6034, Francisco L. F. da Silva 0000-0003-3519-3191, Savarin Sinaviwat 0000-0003-2452-686x, Andrea Raab 0000-0003-2058-0105, Eva M. Krupp, Gisele S. Lopes 0000-0002-9495-1207, Ana R. A. Nogueira 0000-0003-3648-2956 and Joerg Feldmann 0000-0002-0524-8254
pp. 44-54

Environmental context. Intensive aquaculture is the main source of fisheries products. Thus, investigating the food safety of these products and the environmental impacts of the farms on mangroves is necessary. A shrimp productive cycle was evaluated with a focus on trace element accumulation in shrimps and effluent. The results revealed secure levels of elements in the final product; however, the effluent produced in farms is an important source of contamination to mangrove environment.

EN22123Temporal and intra-thallus variation in arsenic species in the brown macroalga Laminaria digitata

Rebecca Sim 0000-0001-7398-8062, Joerg Feldmann 0000-0002-0524-8254, Dagmar B. Stengel 0000-0001-5871-9550 and Ásta H. Pétursdóttir 0000-0002-6739-0598
pp. 55-65

Environmental context. Arsenic contamination has a disproportionate effect on marine ecosystems. Organisms such as some marine macroalgae, which accumulate potentially toxic elements from the surrounding environment, have developed an internal conversion process that is not yet fully understood. Are arsenic-containing sugars a product of detoxification, or simply the result of phospholipid degradation?

EN22069Arsenic speciation of commonly eaten mushrooms from central Europe

Martin Walenta, Simone Braeuer 0000-0002-0975-9051 and Walter Goessler
pp. 66-73

Environmental context. With mushroom consumption increasing worldwide, it is important to know about the concentration of different arsenic species in the most commonly eaten mushroom species, especially since the toxicity depends on the chemical structure. No dangerous amounts of the highly toxic inorganic arsenic were detected in the studied mushrooms. It is therefore safe to consume mushroom fruit-bodies of the investigated species, at least with regard to the arsenic content.

EN22063New arsenic compound identified in rice grain: dimethylarsonyldimethylarsinic acid

Andrea Raab 0000-0003-2058-0105, Kevin Kubachka, Manuela Strohmaier, Marc Preihs and Jörg Feldmann
pp. 74-82
Graphical Abstract Image

Environmental context. The arsenic content and its speciation in harvested rice are dependent on the genetics of the rice variety, the agricultural practise as well as the speciation of arsenic in the soil. The geochemical conditions and therefore the microbiological regime in the paddy fields can influence the biomethylation of the arsenic in the porewater and therefore can influence the extent of arsenic uptake and its speciation in rice plants.


Environmental context. Rice is a staple diet for many people worldwide. Rice accumulates arsenic naturally from soils and is thought to cause straighthead disease. This disease causes sterility in rice resulting in a lack of grain formation and hence the head of the rice remains upright at maturity.


Environmental context. Seaweed is a good natural dietary source of iodine, and some types of seaweed are rich in iodine. Iodine has a diverse chemistry in seaweeds and may exist as different chemical species; however, the occurrence and identity of the individual species are still not fully elucidated. Hence, development of sensitive and selective iodine speciation methods for studies of iodine chemistry and biotransformation in seaweeds are needed.

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