Application of molecularly imprinted polymers in recognition and detection of environmental oestrogens: a review
Cunming Hu
A * , Yu Wang A , Ying Wang B and Ming Guan B *
+ Author Affiliations
- Author Affiliations
A College of Chemistry and Chemical Engineering, Changji University, Changji, 831100, China.
B College of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi, 830054, China.
Cunming Hu graduated from Xinjiang Normal University, China, in 2022. In the same year, he joined Changji University, China. His current research interest is molecularly imprinted polymer-based chemical sensors for food and environmental analysis and detection. |
Yu Wang received master degree from Xinjiang Normal University (2022), and then join in Changji University until now. Her main research interests include the detection of environmental pollutants, the preparation of porous graphene composites and their applications in adsorption and sample preparation. |
Ying Wang is a PhD in analytical chemistry from Xinjiang Normal University, China. Her current research focuses on the construction and application research of SERS sensors with nano-hotspot structure combined with functionalized magnetic materials. |
Ming Guan received his PhD from Xinjiang Medical University, China, in 2011. He was engaged in biological and environmental analysis for many years, has presided over nearly 20 scientific research projects and published more than 70 papers. He is now a professor and doctoral supervisor in Xinjiang Normal University. His research interests include the study of novel materials, such as functionalized nanoparticles for developing nanometer biochemical analysis methods, and molecular imprinting technology. |
Environmental Chemistry 19(8) 461-482 https://doi.org/10.1071/EN22117
Submitted: 17 November 2022 Accepted: 31 January 2023 Published: 2 March 2023
© 2022 The Author(s) (or their employer(s)). Published by CSIRO Publishing.
Environmental context. Environmental oestrogens are a type of endocrine disruptor; their variety, wide range of sources and long-term accumulation in the environment seriously harm the environment ecology and human health. The specific identification, adsorption and detection of environmental oestrogens in the environment, food and drugs is of great significance. Molecularly imprinted polymers (MIPs) have high stability under harsh chemical and physical conditions and involve simple preparation and low cost, which leads to great potential for practical applications. We summarise and discuss recent research advances and future developments of MIP-based monitoring technologies for environmental oestrogens.
Abstract. The growing persistence of environmental oestrogenic pollutants is a worrying concern because of their endocrine disrupting activities and potentially hazardous consequences on environmental matrices, ecology and human health. The long-term persistence of environmental oestrogens leads to their accumulation in the environment and organisms, which in turn reach humans through the food chain pathway. Chronic exposure to environmental oestrogens causes several serious health problems, such as infertility and breast cancer, and affects the development of children’s reproductive system, which illustrates the importance of monitoring and removing environmental oestrogens from the environment. The use of molecularly imprinted polymers (MIPs) for that purpose has acquired a lot of traction in recent years. MIPs are artificial antibodies with selective recognition cavities for specifically targeted substances. They are created using a variety of imprinted polymerisation methods and employed in various pretreatment techniques and numerous types of sensors to be used in a wide range of applications. In this review, we introduce different production methods of MIPs and various analytical strategies for the detection and analysis of environmental oestrogens using MIPs, such as HPLC, electrochemical and optical sensors. Finally, the advantages and limitations of various MIP-based analytical techniques are compared, and the expected future trends and future developments are discussed.
Keywords: chemicals, detection, emoval, environmental analysis, environmental oestrogenic, food safety, molecularly imprinted polymers, sensors.
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