Soil decontamination by natural minerals: a comparison study of chalcopyrite and pyrite
Yanhua Wu A , Yuchan Li A and Hong Wang
A *
+ Author Affiliations
- Author Affiliations
A School of Chemical Engineering & Technology, China University of Mining and Technology, Xuzhou, Jiangsu 221116, P. R. China.
Environmental Chemistry 20(3) 124-136 https://doi.org/10.1071/EN22116
Submitted: 15 November 2022 Accepted: 25 April 2023 Published: 20 June 2023
© 2023 The Author(s) (or their employer(s)). Published by CSIRO Publishing.
Environmental context. With the rapid pace of industrialisation and urbanisation, soil contamination by organic pollutants has become a global focus of concern due to its serious threat to ecosystems and human health. Although a myriad of synthetic catalysts have been developed, natural minerals have the potential to be developed into cost-effective, environmentally benign and efficient catalysts to decontaminate soil. The efficient performance of natural minerals demonstrated in this study indicates a potential for their utilisation in the removal of refractory organic pollutants in soil.
Rationale. Organic pollution of soil has raised worldwide concern owing to the potential effects on ecosystems and human health. Natural metal minerals rich in transition metal elements have the potential to be developed into environmentally benign activators of peroxymonosulfate (PMS) and hydrogen peroxide (H2O2) for soil decontamination.
Methodology. A comparison study employing natural chalcopyrite (NCP) and natural pyrite (NP) as activators in the combined Fenton-like systems of PMS and H2O2 to degrade organic pollutants in soil has been carried out. Tetracycline hydrochloride (TCH) and phenanthrene (PHE) were selected as representatives of widely existing contaminants, antibiotics and polycyclic aromatic hydrocarbons, in the study. Key parameters including initial pH, catalyst and oxidants dosage were also optimised.
Results. A total organic carbon (TOC) removal efficiency of 68.66% was achieved for TCH (500 mg kg–1) with the addition of 0.75 g L–1 NCP, 1.23 mM PMS and 1.23 mM H2O2 within 4 h, whereas a slightly lower mineralisation efficiency of 64.78% was obtained by the NP heterogeneous system. For PHE (50 mg kg–1), 93.04% of TOC was removed using a NCP/PMS/H2O2 process, which was much higher than that of NP (45.76%) after 24 h. The quenching experiments indicated that ˙OH prevailed over 
, and 
also played a vital role in the PMS/H2O2 coupling process.
Discussion. The more superior performance of NCP has been elucidated via X-ray photoelectron spectroscoy analysis and comparison of catalytic mechanisms. The existence of Cu+ played an important role in the transformation of Fe3+ to Fe2+ and facilitated the continuous generation of active radicals. A possible degradation pathway was proposed based on the intermediates identified by GC-MS analysis. We anticipate this study would provide implications for the utilisation of natural minerals in the removal of refractory organic pollutants in soil.
Keywords: chalcopyrite, degradation of organic pollutants, Fenton-like reactions, phenanthrene, PMS/H2O2 activation, pyrite, soil decontamination, tetracycline hydrochloride.
References
Bae S, Kim D, Lee W (2013). Degradation of diclofenac by pyrite catalyzed Fenton oxidation. Applied Catalysis B: Environmental 134–135, 93–102.| Degradation of diclofenac by pyrite catalyzed Fenton oxidation.Crossref | GoogleScholarGoogle Scholar |
Che H, Bae S, Lee W (2011). Degradation of trichloroethylene by Fenton reaction in pyrite suspension. Journal of Hazardous Materials 185, 1355–1361.
| Degradation of trichloroethylene by Fenton reaction in pyrite suspension.Crossref | GoogleScholarGoogle Scholar |
Chen X, Zhao N, Hu X (2022). A novel strategy of pulsed electro-assisted pyrite activation of peroxymonosulfate for the degradation of tetracycline hydrochloride. Separation and Purification Technology 280, 119781
| A novel strategy of pulsed electro-assisted pyrite activation of peroxymonosulfate for the degradation of tetracycline hydrochloride.Crossref | GoogleScholarGoogle Scholar |
Diao Z-H, Zhang W-X, Liang J-Y, Huang S-T, Dong F-X, Yan L, Qian W, Chu W (2021). Removal of herbicide atrazine by a novel biochar based iron composite coupling with peroxymonosulfate process from soil: Synergistic effect and mechanism. Chemical Engineering Journal 409, 127684
| Removal of herbicide atrazine by a novel biochar based iron composite coupling with peroxymonosulfate process from soil: Synergistic effect and mechanism.Crossref | GoogleScholarGoogle Scholar |
Dong D, Li P, Li X, Xu C, Gong D, Zhang Y, Zhao Q, Li P (2010). Photocatalytic degradation of phenanthrene and pyrene on soil surfaces in the presence of nanometer rutile TiO2 under UV-irradiation. Chemical Engineering Journal 158, 378–383.
| Photocatalytic degradation of phenanthrene and pyrene on soil surfaces in the presence of nanometer rutile TiO2 under UV-irradiation.Crossref | GoogleScholarGoogle Scholar |
Feng Y, Wu D, Deng Y, Zhang T, Shih K (2016). Sulfate radical-mediated degradation of sulfadiazine by CuFeO2 rhombohedral crystal-catalyzed peroxymonosulfate: Synergistic effects and mechanisms. Environmental Science & Technology 50, 3119–3127.
| Sulfate radical-mediated degradation of sulfadiazine by CuFeO2 rhombohedral crystal-catalyzed peroxymonosulfate: Synergistic effects and mechanisms.Crossref | GoogleScholarGoogle Scholar |
Fu Y, Ren Z, Wu J, Li Y, Liu W, Li P, Xing L, Ma J, Wang H, Xue X (2021). Direct Z-scheme heterojunction of ZnO/MoS2 nanoarrays realized by flowing-induced piezoelectric field for enhanced sunlight photocatalytic performances. Applied Catalysis B: Environmental 285, 119785
| Direct Z-scheme heterojunction of ZnO/MoS2 nanoarrays realized by flowing-induced piezoelectric field for enhanced sunlight photocatalytic performances.Crossref | GoogleScholarGoogle Scholar |
Gu M, Sui Q, Farooq U, Zhang X, Qiu Z, Lyu S (2018). Degradation of phenanthrene in sulfate radical based oxidative environment by nZVI-PDA functionalized rGO catalyst. Chemical Engineering Journal 354, 541–552.
| Degradation of phenanthrene in sulfate radical based oxidative environment by nZVI-PDA functionalized rGO catalyst.Crossref | GoogleScholarGoogle Scholar |
Guo R, Wang Y, Li J, Cheng X, Dionysiou DD (2020). Sulfamethoxazole degradation by visible light assisted peroxymonosulfate process based on nanohybrid manganese dioxide incorporating ferric oxide. Applied Catalysis B: Environmental 278, 119297
| Sulfamethoxazole degradation by visible light assisted peroxymonosulfate process based on nanohybrid manganese dioxide incorporating ferric oxide.Crossref | GoogleScholarGoogle Scholar |
Hayati F, Moradi S, Farshineh Saei S, Madani Z, Giannakis S, Isari AA, Kakavandi B (2022). A novel, Z-scheme ZnO@AC@FeO photocatalyst, suitable for the intensification of photo-mediated peroxymonosulfate activation: Performance, reactivity and bisphenol A degradation pathways. Journal of Environmental Management 321, 115851
| A novel, Z-scheme ZnO@AC@FeO photocatalyst, suitable for the intensification of photo-mediated peroxymonosulfate activation: Performance, reactivity and bisphenol A degradation pathways.Crossref | GoogleScholarGoogle Scholar |
Hu L, Zhang G, Liu M, Wang Q, Wang P (2018). Enhanced degradation of Bisphenol A (BPA) by peroxymonosulfate with Co3O4-Bi2O3 catalyst activation: Effects of pH, inorganic anions, and water matrix. Chemical Engineering Journal 338, 300–310.
| Enhanced degradation of Bisphenol A (BPA) by peroxymonosulfate with Co3O4-Bi2O3 catalyst activation: Effects of pH, inorganic anions, and water matrix.Crossref | GoogleScholarGoogle Scholar |
Huang B, Yan D, Wang X, Wang X, Fang W, Zhang D, Ouyang C, Wang Q, Cao A (2019). Soil fumigation alters adsorption and degradation behavior of pesticides in soil. Environmental Pollution 246, 264–273.
| Soil fumigation alters adsorption and degradation behavior of pesticides in soil.Crossref | GoogleScholarGoogle Scholar |
Imran MA, Tong Y, Hu Q, Liu M, Chen H (2020). Effects of persulfate activation with pyrite and zero-valent iron for phthalate acid ester degradation. Water 12, 354
| Effects of persulfate activation with pyrite and zero-valent iron for phthalate acid ester degradation.Crossref | GoogleScholarGoogle Scholar |
Kakavandi B, Dehghanifard E, Gholami P, Noorisepehr M, MirzaHedayat B (2021). Photocatalytic activation of peroxydisulfate by magnetic Fe3O4@SiO2@TiO2/rGO core-shell towards degradation and mineralization of metronidazole. Applied Surface Science 570, 151145
| Photocatalytic activation of peroxydisulfate by magnetic Fe3O4@SiO2@TiO2/rGO core-shell towards degradation and mineralization of metronidazole.Crossref | GoogleScholarGoogle Scholar |
Kakavandi B, Alavi S, Ghanbari F, Ahmadi M (2022). Bisphenol A degradation by peroxymonosulfate photo-activation coupled with carbon-based cobalt ferrite nanocomposite: Performance, upgrading synergy and mechanistic pathway. Chemosphere 287, 132024
| Bisphenol A degradation by peroxymonosulfate photo-activation coupled with carbon-based cobalt ferrite nanocomposite: Performance, upgrading synergy and mechanistic pathway.Crossref | GoogleScholarGoogle Scholar |
Kang G, Lee S, Keum H, Chung N (2018). Degradation of pyrene contaminated soil with spiked 14C pyrene by hemoglobin catalysis. Topics in Catalysis 61, 1665–1671.
| Degradation of pyrene contaminated soil with spiked 14C pyrene by hemoglobin catalysis.Crossref | GoogleScholarGoogle Scholar |
Lee S-H, Lee W-S, Lee C-H, Kim J-G (2008). Degradation of phenanthrene and pyrene in rhizosphere of grasses and legumes. Journal of Hazardous Materials 153, 892–898.
| Degradation of phenanthrene and pyrene in rhizosphere of grasses and legumes.Crossref | GoogleScholarGoogle Scholar |
Li Y-S, Jiang F-L, Xiao Q, Li R, Li K, Zhang M-F, Zhang A-Q, Sun S-F, Liu Y (2010). Enhanced photocatalytic activities of TiO2 nanocomposites doped with water-soluble mercapto-capped CdTe quantum dots. Applied Catalysis B: Environmental 101, 118–129.
| Enhanced photocatalytic activities of TiO2 nanocomposites doped with water-soluble mercapto-capped CdTe quantum dots.Crossref | GoogleScholarGoogle Scholar |
Li H, Yao Y, Zhang J, Du J, Xu S, Wang C, Zhang D, Tang J, Zhao H, Zhou J (2020a). Degradation of phenanthrene by peroxymonosulfate activated with bimetallic metal-organic frameworks: Kinetics, mechanisms, and degradation products. Chemical Engineering Journal 397, 125401
| Degradation of phenanthrene by peroxymonosulfate activated with bimetallic metal-organic frameworks: Kinetics, mechanisms, and degradation products.Crossref | GoogleScholarGoogle Scholar |
Li Y, Li D, Lai L, Li Y (2020b). Remediation of petroleum hydrocarbon contaminated soil by using activated persulfate with ultrasound and ultrasound/Fe. Chemosphere 238, 124657
| Remediation of petroleum hydrocarbon contaminated soil by using activated persulfate with ultrasound and ultrasound/Fe.Crossref | GoogleScholarGoogle Scholar |
Li T, Abdelhaleem A, Chu W, Xu W (2021a). Efficient activation of oxone by pyrite for the degradation of propanil: kinetics and degradation pathway. Journal of Hazardous Materials 403, 123930
| Efficient activation of oxone by pyrite for the degradation of propanil: kinetics and degradation pathway.Crossref | GoogleScholarGoogle Scholar |
Li Y, Dong H, Li L, Xiao J, Xiao S, Jin Z (2021b). Efficient degradation of sulfamethazine via activation of percarbonate by chalcopyrite. Water Research 202, 117451
| Efficient degradation of sulfamethazine via activation of percarbonate by chalcopyrite.Crossref | GoogleScholarGoogle Scholar |
Li Z, Wang F, Zhang Y, Lai Y, Fang Q, Duan Y (2021c). Activation of peroxymonosulfate by CuFe2O4-CoFe2O4 composite catalyst for efficient bisphenol a degradation: Synthesis, catalytic mechanism and products toxicity assessment. Chemical Engineering Journal 423, 130093
| Activation of peroxymonosulfate by CuFe2O4-CoFe2O4 composite catalyst for efficient bisphenol a degradation: Synthesis, catalytic mechanism and products toxicity assessment.Crossref | GoogleScholarGoogle Scholar |
Li Y, Yu B, Hu Z, Wang H (2022). Construction of direct Z-scheme SnS2@ZnIn2S4@kaolinite heterostructure photocatalyst for efficient photocatalytic degradation of tetracycline hydrochloride. Chemical Engineering Journal 429, 132105
| Construction of direct Z-scheme SnS2@ZnIn2S4@kaolinite heterostructure photocatalyst for efficient photocatalytic degradation of tetracycline hydrochloride.Crossref | GoogleScholarGoogle Scholar |
Liu S-H, Zeng G-M, Niu Q-Y, Liu Y, Zhou L, Jiang L-H, Tan X, Xu P, Zhang C, Cheng M (2017). Bioremediation mechanisms of combined pollution of PAHs and heavy metals by bacteria and fungi: A mini review. Bioresource Technology 224, 25–33.
| Bioremediation mechanisms of combined pollution of PAHs and heavy metals by bacteria and fungi: A mini review.Crossref | GoogleScholarGoogle Scholar |
Liu Y, Wang Y, Wang Q, Pan J, Zhang J (2018). Simultaneous removal of NO and SO2 using vacuum ultraviolet light (VUV)/heat/peroxymonosulfate (PMS). Chemosphere 190, 431–441.
| Simultaneous removal of NO and SO2 using vacuum ultraviolet light (VUV)/heat/peroxymonosulfate (PMS).Crossref | GoogleScholarGoogle Scholar |
Liu C, Chen X, Mack EE, Wang S, Du W, Yin Y, Banwart SA, Guo H (2019). Evaluating a novel permeable reactive bio-barrier to remediate PAH-contaminated groundwater. Journal of Hazardous Materials 368, 444–451.
| Evaluating a novel permeable reactive bio-barrier to remediate PAH-contaminated groundwater.Crossref | GoogleScholarGoogle Scholar |
Luo Z, Min Y, Qu L, Song Y, Hong Y (2021). Remediation of phenanthrene contaminated soil by ferrous oxalate and its phytotoxicity evaluation. Chemosphere 265, 129070
| Remediation of phenanthrene contaminated soil by ferrous oxalate and its phytotoxicity evaluation.Crossref | GoogleScholarGoogle Scholar |
Manz KE, Carter KE (2018). Degradation of hydraulic fracturing additive 2-butoxyethanol using heat activated persulfate in the presence of shale rock. Chemosphere 206, 398–404.
| Degradation of hydraulic fracturing additive 2-butoxyethanol using heat activated persulfate in the presence of shale rock.Crossref | GoogleScholarGoogle Scholar |
Moradi M, Kakavandi B, Bahadoran A, Giannakis S, Dehghanifard E (2022). Intensification of persulfate-mediated elimination of bisphenol A by a spinel cobalt ferrite-anchored g-C3N4 S-scheme photocatalyst: Catalytic synergies and mechanistic interpretation. Separation and Purification Technology 285, 120313
| Intensification of persulfate-mediated elimination of bisphenol A by a spinel cobalt ferrite-anchored g-C3N4 S-scheme photocatalyst: Catalytic synergies and mechanistic interpretation.Crossref | GoogleScholarGoogle Scholar |
Nie W, Mao Q, Ding Y, Hu Y, Tang H (2019). Highly efficient catalysis of chalcopyrite with surface bonded ferrous species for activation of peroxymonosulfate toward degradation of bisphenol A: A mechanism study. Journal of Hazardous Materials 364, 59–68.
| Highly efficient catalysis of chalcopyrite with surface bonded ferrous species for activation of peroxymonosulfate toward degradation of bisphenol A: A mechanism study.Crossref | GoogleScholarGoogle Scholar |
Pandey VC, Bajpai O, Singh N (2016). Energy crops in sustainable phytoremediation. Renewable and Sustainable Energy Reviews 54, 58–73.
| Energy crops in sustainable phytoremediation.Crossref | GoogleScholarGoogle Scholar |
Peng J, Zhou H, Liu W, Ao Z, Ji H, Liu Y, Su S, Yao G, Lai B (2020). Insights into heterogeneous catalytic activation of peroxymonosulfate by natural chalcopyrite: pH-dependent radical generation, degradation pathway and mechanism. Chemical Engineering Journal 397, 125387
| Insights into heterogeneous catalytic activation of peroxymonosulfate by natural chalcopyrite: pH-dependent radical generation, degradation pathway and mechanism.Crossref | GoogleScholarGoogle Scholar |
Qi C, Liu X, Ma j, Lin C, Li X, Zhang H (2016). Activation of peroxymonosulfate by base: implications for the degradation of organic pollutants. Chemosphere 151, 280–288.
| Activation of peroxymonosulfate by base: implications for the degradation of organic pollutants.Crossref | GoogleScholarGoogle Scholar |
Ren Z, Xie J, Li X, Guo L, Zhang Q, Wu J, Li Y, Liu W, Li P, Fu Y, Zhao K, Ma J (2023). Rational design of graphite carbon nitride-decorated zinc oxide nanoarrays on three-dimensional nickel foam for the efficient production of reactive oxygen species through stirring-promoted piezo-photocatalysis. Journal of Colloid and Interface Science 632, 271–284.
| Rational design of graphite carbon nitride-decorated zinc oxide nanoarrays on three-dimensional nickel foam for the efficient production of reactive oxygen species through stirring-promoted piezo-photocatalysis.Crossref | GoogleScholarGoogle Scholar |
Sang W, Li Z, Huang M, Wu X, Li D, Mei L, Cui J (2020). Enhanced transition metal oxide based peroxymonosulfate activation by hydroxylamine for the degradation of sulfamethoxazole. Chemical Engineering Journal 383, 123057
| Enhanced transition metal oxide based peroxymonosulfate activation by hydroxylamine for the degradation of sulfamethoxazole.Crossref | GoogleScholarGoogle Scholar |
Shi Y, Li J, Wan D, Huang J, Liu Y (2020). Peroxymonosulfate-enhanced photocatalysis by carbonyl-modified g-C3N4 for effective degradation of the tetracycline hydrochloride. Science of the Total Environment 749, 142313
| Peroxymonosulfate-enhanced photocatalysis by carbonyl-modified g-C3N4 for effective degradation of the tetracycline hydrochloride.Crossref | GoogleScholarGoogle Scholar |
Sun Y, Feng L, Yang L (2021). Degradation of PCB67 in soil using the heterogenous Fenton process induced by montmorillonite supported nanoscale zero-valent iron. Journal of Hazardous Materials 406, 124305
| Degradation of PCB67 in soil using the heterogenous Fenton process induced by montmorillonite supported nanoscale zero-valent iron.Crossref | GoogleScholarGoogle Scholar |
Usman M, Hanna K, Faure P (2018). Remediation of oil-contaminated harbor sediments by chemical oxidation. Science of the Total Environment 634, 1100–1107.
| Remediation of oil-contaminated harbor sediments by chemical oxidation.Crossref | GoogleScholarGoogle Scholar |
Usman M, Jellali S, Anastopoulos I, Charabi Y, Hameed BH, Hanna K (2022). Fenton oxidation for soil remediation: A critical review of observations in historically contaminated soils. Journal of Hazardous Materials 424, 127670
| Fenton oxidation for soil remediation: A critical review of observations in historically contaminated soils.Crossref | GoogleScholarGoogle Scholar |
Wang J, Wang S (2018). Activation of persulfate (PS) and peroxymonosulfate (PMS) and application for the degradation of emerging contaminants. Chemical Engineering Journal 334, 1502–1517.
| Activation of persulfate (PS) and peroxymonosulfate (PMS) and application for the degradation of emerging contaminants.Crossref | GoogleScholarGoogle Scholar |
Wang X, Wang Y, Chen N, Shi Y, Zhang L (2020). Pyrite enables persulfate activation for efficient atrazine degradation. Chemosphere 244, 125568
| Pyrite enables persulfate activation for efficient atrazine degradation.Crossref | GoogleScholarGoogle Scholar |
Wang C, Sun R, Huang R, Cao Y (2021). A novel strategy for enhancing heterogeneous Fenton degradation of dye wastewater using natural pyrite: Kinetics and mechanism. Chemosphere 272, 129883
| A novel strategy for enhancing heterogeneous Fenton degradation of dye wastewater using natural pyrite: Kinetics and mechanism.Crossref | GoogleScholarGoogle Scholar |
Yan N, Liu F, Huang W (2013). Interaction of oxidants in siderite catalyzed hydrogen peroxide and persulfate system using trichloroethylene as a target contaminant. Chemical Engineering Journal 219, 149–154.
| Interaction of oxidants in siderite catalyzed hydrogen peroxide and persulfate system using trichloroethylene as a target contaminant.Crossref | GoogleScholarGoogle Scholar |
Yin R, Guo W, Wang H, Du J, Zhou X, Wu Q, Zheng H, Chang J, Ren N (2018). Selective degradation of sulfonamide antibiotics by peroxymonosulfate alone: direct oxidation and nonradical mechanisms. Chemical Engineering Journal 334, 2539–2546.
| Selective degradation of sulfonamide antibiotics by peroxymonosulfate alone: direct oxidation and nonradical mechanisms.Crossref | GoogleScholarGoogle Scholar |
Yu S, Gu X, Lu S, Xue Y, Zhang X, Xu M, Qiu Z, Sui Q (2018). Degradation of phenanthrene in aqueous solution by a persulfate/percarbonate system activated with CA chelated-Fe(II). Chemical Engineering Journal 333, 122–131.
| Degradation of phenanthrene in aqueous solution by a persulfate/percarbonate system activated with CA chelated-Fe(II).Crossref | GoogleScholarGoogle Scholar |
Yuan X, Li T, He Y, Xue N (2021). Degradation of TBBPA by nZVI activated persulfate in soil systems. Chemosphere 284, 131166
| Degradation of TBBPA by nZVI activated persulfate in soil systems.Crossref | GoogleScholarGoogle Scholar |
Zhao X, Cai Z, Wang T, O’Reilly SE, Liu W, Zhao D (2016). A new type of cobalt-deposited titanate nanotubes for enhanced photocatalytic degradation of phenanthrene. Applied Catalysis B: Environmental 187, 134–143.
| A new type of cobalt-deposited titanate nanotubes for enhanced photocatalytic degradation of phenanthrene.Crossref | GoogleScholarGoogle Scholar |
Zhao H, Huang X, Wang J, Li Y, Liao R, Wang X, Qiu X, Xiong Y, Qin W, Qiu G (2017). Comparison of bioleaching and dissolution process of p-type and n-type chalcopyrite. Minerals Engineering 109, 153–161.
| Comparison of bioleaching and dissolution process of p-type and n-type chalcopyrite.Crossref | GoogleScholarGoogle Scholar |
Zhao Y, Song M, Cao Q, Sun P, Chen Y, Meng F (2020). The superoxide radicals’ production via persulfate activated with CuFe2O4@Biochar composites to promote the redox pairs cycling for efficient degradation of o-nitrochlorobenzene in soil. Journal of Hazardous Materials 400, 122887
| The superoxide radicals’ production via persulfate activated with CuFe2O4@Biochar composites to promote the redox pairs cycling for efficient degradation of o-nitrochlorobenzene in soil.Crossref | GoogleScholarGoogle Scholar |
Zheng H, Bao J, Huang Y, Xiang L, Faheem , Ren B, Du J, Nadagouda MN, Dionysiou DD (2019). Efficient degradation of atrazine with porous sulfurized Fe2O3 as catalyst for peroxymonosulfate activation. Applied Catalysis B: Environmental 259, 118056
| Efficient degradation of atrazine with porous sulfurized Fe2O3 as catalyst for peroxymonosulfate activation.Crossref | GoogleScholarGoogle Scholar |
Zhong D, Zhou Z, Ma W, Ma J, Lv W, Feng W, Du X, He F (2022). Study on degradation of chloramphenicol by H2O2/PMS double-oxidation system catalyzed by pipe deposits from water networks. Journal of Environmental Chemical Engineering 10, 107529
| Study on degradation of chloramphenicol by H2O2/PMS double-oxidation system catalyzed by pipe deposits from water networks.Crossref | GoogleScholarGoogle Scholar |
