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RESEARCH ARTICLE
Contents Vol 6(1)

Relationship between oxidative degradation of 2-mercaptobenzothiazole and physicochemical properties of manganese (hydro)oxides

C. S. Liu A C , L. J. Zhang A , C. H. Feng B , C. A. Wu A , F. B. Li A D and X. Z. Li C
+ Author Affiliations
- Author Affiliations

A Guangdong Key Laboratory of Agricultural Environment Pollution Integrated Control, Guangdong Institute of Eco-Environmental and Soil Sciences, No. 808, Tianyuan Road, Guangzhou 510650, China.

B School of Chemistry and Chemical Engineering, South China University of Technology, No. 381, Wushan Road, Guangzhou 510640, China.

C Department of Civil and Structural Engineering, The Hong Kong Polytechnic University, Hung Hom, Hong Kong 999077, China.

D Corresponding author. Email: cefbli@soil.gd.cn

Environmental Chemistry 6(1) 83-92 https://doi.org/10.1071/EN08053
Submitted: 11 August 2008  Accepted: 8 January 2009   Published: 3 March 2009

Environmental context. Manganese (hydro)oxide is one kind of the most important natural minerals that are capable of oxidising organic contaminants with a wide range of functionality. However, the oxidative reactivity of manganese (hydro)oxides for organic pollutant degradation may depend on their individual physicochemical properties. It is important to determine a relationship between their oxidative reactivity and physicochemical properties.

Abstract. The oxidative reactivity of manganese (hydro)oxides is important for geochemical transformation of organic pollutants. Here, 2-mercaptobenzothiazole (MBT) degradation by six manganese (hydro)oxides, including γ-MnOOH, β-MnO2, α-MnO2, γ-Mn2O3, δ-MnO2, and MO-700, were investigated with different initial MBT concentrations, manganese (hydro)oxide dosages and pH values. The results show the oxidative reactivity of manganese (hydro)oxides towards MBT degradation strongly depends on their physicochemical properties. Specific surface area and reduction potential of manganese (hydro)oxides were positively correlated with MBT degradation rates, whereas pH at the point of zero charge (pHPZC) of manganese (hydro)oxides and apparent activation energy (Ea) were negatively correlated. A high average oxidation state with the same chemical valence always corresponds to high oxidative reactivity. Such findings provide some insights into understanding the transport and fate of organic pollutants in the presence of different manganese (hydro)oxides in the natural environment.

Additional keywords: correlative analysis, manganese oxides, organic pollutants, oxidation.


Acknowledgements

The work was financially supported by the National Natural Science Foundation of People’s Republic of China (20577007).


References


[1]   P. A. Hansson , S. E. Svensson , F. Hallefalt , H. Diedrichs , Nutrient and cost optimization of fertilizing strategies for Salix including use of organic waste products. Biomass Bioenergy 1999 , 17,  377.
        | Crossref | GoogleScholarGoogle Scholar |  open url image1

[2]   D. A. Bright , N. Healey , Contaminant risks from biosolids land application: contemporary organic contaminant levels in digested sewage sludge from five treatment plants in Greater Vancouver, British Columbia. Environ. Pollut. 2003 , 126,  39.
        | Crossref | GoogleScholarGoogle Scholar | CAS | PubMed |  open url image1

[3]   P. M. Huang , M. K. Wang , C. Y. Chiu , Soil mineral–organic matter–microbe interactions: impacts on biogeochemical processes and biodiversity in soils. Pedobiologia 2005 , 49,  609.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[4]   K. J. Doick , P. Burauel , K. C. Jones , K. T. Semple , Distribution of aged 14C-PCB and 14C-PAH residues in particle-size and humic fractions of an agricultural soil. Environ. Sci. Technol. 2005 , 39,  6575.
        | Crossref | GoogleScholarGoogle Scholar | CAS | PubMed |  open url image1

[5]   P. W. Abrahams , Soils: their implications to human health. Sci. Total Environ. 2002 , 291,  1.
        | Crossref | GoogleScholarGoogle Scholar | CAS | PubMed |  open url image1

[6]   S. Paria , Surfactant-enhanced remediation of organic contaminated soil and water. Adv. Colloid Interface Sci. 2008 , 138,  24.
        | Crossref | GoogleScholarGoogle Scholar | CAS | PubMed |  open url image1

[7]   A. R. Zimmerman , K. W. Goyne , J. Chorover , S. Komarneni , S. L. Brantley , Mineral mesopore effects on nitrogenous organic matter adsorption. Org. Geochem. 2004 , 35,  355.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[8]   H. C. Zhang , C. H. Huang , Oxidative transformation of fluoroquinolone antibacterial agents and structurally related amines by manganese oxide. Environ. Sci. Technol. 2005 , 39,  4474.
        | Crossref | GoogleScholarGoogle Scholar | CAS | PubMed |  open url image1

[9]   H. Li , L. S. Lee , D. G. Schulze , C. A. Guest , Role of soil manganese in the oxidation of aromatic amines. Environ. Sci. Technol. 2003 , 37,  2686.
        | Crossref | GoogleScholarGoogle Scholar | CAS | PubMed |  open url image1

[10]   L. Zhao , P. Peng , Z. Yu , W. Huang , S. Feng , H. Zhou , Oxidation kinetics of pentachlorophenol by manganese dioxide. Environ. Toxicol. Chem. 2006 , 25,  2912.
        | Crossref | GoogleScholarGoogle Scholar | CAS | PubMed |  open url image1

[11]   H. C. Zhang , C. H. Huang , Oxidative transformation of triclosan and chlorophene by manganese oxides. Environ. Sci. Technol. 2003 , 37,  2421.
        | Crossref | GoogleScholarGoogle Scholar | CAS | PubMed |  open url image1

[12]   J. Klausen , S. B. Haderlein , R. P. Schwarzenbach , Oxidation of substituted anilines by aqueous MnO2: effect of co-solutes on initial and quasi-steady-state kinetics. Environ. Sci. Technol. 1997 , 31,  2642.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[13]   S. Laha , R. G. Luthy , Oxidation of aniline and other primary aromatic amines by manganese dioxide. Environ. Sci. Technol. 1990 , 24,  363.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[14]   J. L. Yu , P. E. Savage , Kinetics of MnO2-catalyzed acetic acid oxidation in supercritical water. Ind. Eng. Chem. Res. 2000 , 39,  4014.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[15]   K. F. Rubert , J. A. Pedersen , Kinetics of oxytetracycline reaction with a hydrous manganese oxide. Environ. Sci. Technol. 2006 , 40,  7216.
        | Crossref | GoogleScholarGoogle Scholar | CAS | PubMed |  open url image1

[16]   J. Y. Shin , M. A. Cheney , Abiotic transformation of atrazine in aqueous suspension of four synthetic manganese oxides. Colloid Surf. A 2004 , 242,  85.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[17]   K. E. Kress , Spectrophotometric analysis of accelerator-rubber mixtures. Anal. Chem. 1951 , 23,  313.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[18]   S. Ching , D. J. Petrovay , M. L. Jorgensen , S. L. Suib , Sol-gel synthesis of layered birnessite-type manganese oxides. Inorg. Chem. 1997 , 36,  883.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[19]   W. X. Zhang , Z. H. Yang , Y. Liu , S. P. Tang , X. Z. Han , M. Chen , Controlled synthesis of Mn3O4 nanocrystallites and MnOOH nanorods by a solvothermal method. J. Cryst. Growth 2004 , 263,  394.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[20]   F. B. Li , C. S. Liu , C. H. Liang , X. Z. Li , L. J. Zhang , The oxidative degradation of 2-mercaptobenzothiazole at the interface of β-MnO2 and water. J. Hazard. Mater. 2008 , 154,  1098.
        | Crossref | GoogleScholarGoogle Scholar | CAS | PubMed |  open url image1

[21]   J. G. Yu , J. C. Yu , M. K. P. Leung , W. K. Ho , B. Cheng , X. J. Zhao , J. C. Zhao , Effects of acidic and basic hydrolysis catalysts on the photocatalytic activity and microstructures of bimodal mesoporous titania. J. Catal. 2003 , 217,  69.
        |  CAS |  open url image1

[22]   G. G. Xia , W. Tong , E. N. Tolentino , N. G. Duan , S. L. Brock , J. Y. Wang , S. L. Suib , T. Ressler , Synthesis and characterization of nanofibrous sodium manganese oxide with a 2 × 4 tunnel structure. Chem. Mater. 2001 , 13,  1585.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[23]   W. F. Tan , S. J. Lu , F. Liu , X. H. Feng , J. Z. He , L. K. Koopall , Determination of the point-of-zero charge of manganese oxides with different methods including an improved salt titration method. Soil Sci. 2008 , 173,  277.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[24]   J. D. Danforth , J. Indiveri , Activation energies and frequency factors for the dehydrochlorination of polyvinyl-chloride from the Arrhenius equation. J. Phys. Chem. 1983 , 87,  5376.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[25]   C. K. Lee , C. S. Tsay , Surface fractal dimensions of alumina and aluminium borate from nitrogen isotherms. J. Phys. Chem. B 1998 , 102,  4123.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[26]   M. F. Lengke , R. N. Tempel , Natural realgar and amorphous AsS oxidation kinetics. Geochim. Cosmochim. Acta 2003 , 67,  859.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[27]   S. Murphy , G. B. Schuster , A kinetic method for determination of redox potentials – oxidation of tetraarylborates. J. Phys. Chem. 1995 , 99,  511.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[28]   Morrison S. R., The Chemical Physics of Surfaces 1997 (Plenum Press: New York).

[29]   R. Woods , G. A. Hope , K. Watling , Surface-enhanced Raman scattering spectroscopic studies of the adsorption of flotation collectors. Miner. Eng. 2000 , 13,  345.
        | Crossref | GoogleScholarGoogle Scholar | CAS |  open url image1

[30]   Cramer A. C., Oxidation of pentachlorophenol on manganese oxide surfaces 1995, M.Sc. thesis, Utah State University, Logan, UT.

[31]   Denisov E. T., Denisov T. D., Handbook of Antioxidants: Bond Dissociation Energies, Rates Constants, Activation Energies, and Enthalpies of Reactions 1999 (CRC: New York).