Free Standard AU & NZ Shipping For All Book Orders Over $80!
Register      Login
Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
Shopping Cart: ( empty )
You are here: Home > Journals > CH > CH21317 > Fulltext
RESEARCH ARTICLE
Contents Vol 75(9)

Coordination polymers based on aluminum and indium halides together with pyrazine†

Thomas C. Schäfer A , Jonathan Becker A , Dominik Heuler A , Marcel T. Seuffert A , Alexander E. Sedykh A and Klaus Müller-Buschbaum https://orcid.org/0000-0002-2857-8379 A B *
+ Author Affiliations
- Author Affiliations

A Institute of Inorganic and Analytical Chemistry, Justus-Liebig University Giessen, Heinrich-Buff-Ring 17, 35392 Giessen, Germany.

B Center for Materials Research (LaMa), Justus-Liebig University Giessen, Heinrich-Buff-Ring 16, 35392 Giessen, Germany.

* Correspondence to: kmbac@uni-giessen.de

Handling Editor: George Koutsantonis

Australian Journal of Chemistry 75(9) 676-683 https://doi.org/10.1071/CH21317
Submitted: 1 December 2021  Accepted: 3 February 2022   Published: 7 April 2022

© 2022 The Author(s) (or their employer(s)). Published by CSIRO Publishing.

Abstract

Four structurally closely related one-dimensional coordination polymers (CPs) have been synthesised, constituted by pyrazine (pyz) and the group 13 metal halides AlCl3, AlI3, InBr3, and InI3. Three CPs are isotypic: CH21317_IE1.gif, CH21317_IE2.gif, CH21317_IE3.gif. Alike CH21317_IE4.gif, they form linear chains. Hereby, each M3+ ion is trigonal-bipyramidally coordinated by three halido ligands and two N-atoms of two pyz serving as linear nodes with twofold connectivity (2-c). The CPs were characterised by SCXRD, PXRD, elemental-analysis, simultaneous DTA/TG and IR-spectroscopy. In addition, two complexes [(AlCl3)2(pyz)5] and [(InI3)2(pyz)] with octahedrally coordinated Al3+ and unprecedented tetrahedrally coordinated In3+ ions were structurally characterised by SCXRD.

Keywords: aluminum, bromide, chloride, coordination polymer, group 13 elements, indium, iodide, N-ligands, Pyrazine.


References

[1]  Batten SR, Neville SM, Turner DR. Coordination Polymers. Design, Analysis and Application. Cambrige: R. Soc. Chem.; 2009. p. 424.
| Crossref |

[2]  C Janiak, Dalton Trans 2003, 14, 2781.
         | Crossref | GoogleScholarGoogle Scholar |

[3]  C Janiak, JK Vieth, New J Chem 2010, 34, 2366.
         | Crossref | GoogleScholarGoogle Scholar |

[4]  S Kitagawa, R Matsuda, Coord Chem Rev 2007, 251, 2490.
         | Crossref | GoogleScholarGoogle Scholar |

[5]  SR Batten, NR Champness, X-M Chen, J Garcia-Martinez, S Kitagawa, L Öhrström, M O’Keeffe, M Paik Suh, J Reedijk, Pure Appl Chem 2013, 85, 1715.
         | Crossref | GoogleScholarGoogle Scholar |

[6]  SR Batten, NR Champness, X-M Chen, J Garcia-Martinez, S Kitagawa, L Öhrström, M O’Keeffe, MP Suh, J Reedijk, CrystEngComm 2012, 14, 3001.
         | Crossref | GoogleScholarGoogle Scholar |

[7]  S Bauer, N Stock, Chem Unserer Zeit 2008, 42, 12.
         | Crossref | GoogleScholarGoogle Scholar |

[8]  G Férey, Chem Soc Rev 2008, 37, 191.
         | Crossref | GoogleScholarGoogle Scholar | 18197340PubMed |

[9]  S Kitagawa, K Uemura, Chem Soc Rev 2005, 34, 109.
         | Crossref | GoogleScholarGoogle Scholar | 15672175PubMed |

[10]  JR Long, OM Yaghi, Chem Soc Rev 2009, 38, 1213.
         | Crossref | GoogleScholarGoogle Scholar | 19384431PubMed |

[11]  AE Baumann, DA Burns, B Liu, VS Thoi, Commun Chem 2019, 2, 86.
         | Crossref | GoogleScholarGoogle Scholar |

[12]  J Heine, K Müller-Buschbaum, Chem Soc Rev 2013, 42, 9232.
         | Crossref | GoogleScholarGoogle Scholar | 24077361PubMed |

[13]  S Kitagawa, R Kitaura, S-I Noro, Angew Chem Int Ed 2004, 43, 2334.
         | Crossref | GoogleScholarGoogle Scholar |

[14]  M Kurmoo, Chem Soc Rev 2009, 38, 1353.
         | Crossref | GoogleScholarGoogle Scholar | 19384442PubMed |

[15]  C Wang, T Zhang, W Lin, Chem Rev 2012, 112, 1084.
         | Crossref | GoogleScholarGoogle Scholar | 22070202PubMed |

[16]  Q Wang, D Astruc, Chem Rev 2020, 120, 1438.
         | Crossref | GoogleScholarGoogle Scholar | 31246430PubMed |

[17]  IA Baburin, VA Blatov, L Carlucci, G Ciani, DM Proserpio, CrystEngComm 2008, 10, 1822.
         | Crossref | GoogleScholarGoogle Scholar |

[18]  Batten SR. In: Gale PA, Steed JW, Editors. In Supramolecular Chemistry: From Molecules to Nanomaterials, Vol. 6. Chichester: Wiley; 2012. pp. 3107–3120.
| Crossref |

[19]  W Gebert, Acta Crystallogr, Sect B 1978, 34, 2958.
         | Crossref | GoogleScholarGoogle Scholar |

[20]  Y-N Gong, D-C Zhong, T-B Lu, CrystEngComm 2016, 18, 2596.
         | Crossref | GoogleScholarGoogle Scholar |

[21]  S Natarajan, P Mahata, Chem Soc Rev 2009, 38, 2304.
         | Crossref | GoogleScholarGoogle Scholar | 19623352PubMed |

[22]  M O’Keeffe, MA Peskov, SJ Ramsden, OM Yaghi, Acc Chem Res 2008, 41, 1782.
         | Crossref | GoogleScholarGoogle Scholar | 18834152PubMed |

[23]  LM Aguirre-Díaz, D Reinares-Fisac, M Iglesias, E Gutiérrez-Puebla, F Gándara, N Snejko, MÁ Monge, Coord Chem Rev 2017, 335, 1.
         | Crossref | GoogleScholarGoogle Scholar |

[24]  AV Desai, S Sharma, S Let, SK Ghosh, Coord Chem Rev 2019, 395, 146.
         | Crossref | GoogleScholarGoogle Scholar |

[25]  JR Sorg, TC Schäfer, T Schneider, K Müller-Buschbaum, Z Anorg Allg Chem 2020, 646, 507.
         | Crossref | GoogleScholarGoogle Scholar |

[26]  SC James, NC Norman, A Guy Orpen, J Starbuck, CrystEngComm 2000, 2, 67.
         | Crossref | GoogleScholarGoogle Scholar |

[27]  AV Desai, S Sharma, A Roy, MM Shirolkar, SK Ghosh, Mol Syst Des Eng 2020, 5, 469.
         | Crossref | GoogleScholarGoogle Scholar |

[28]  JM Harrowfield, H Miyamae, BW Skelton, AA Soudi, AH White, Aust J Chem 1996, 49, 1157.
         | Crossref | GoogleScholarGoogle Scholar |

[29]  J-J Liu, Y Chen, M-J Lin, C-C Huang, W-X Dai, Dalton Trans 2016, 45, 6339.
         | Crossref | GoogleScholarGoogle Scholar | 26985714PubMed |

[30]  JR Sorg, T Schneider, L Wohlfarth, TC Schäfer, A Sedykh, K Müller-Buschbaum, Dalton Trans 2020, 49, 4904.
         | Crossref | GoogleScholarGoogle Scholar | 32232237PubMed |

[31]  JR Sorg, T Wehner, PR Matthes, R Sure, S Grimme, J Heine, K Müller-Buschbaum, Dalton Trans 2018, 47, 7669.
         | Crossref | GoogleScholarGoogle Scholar | 29766175PubMed |

[32]  AF Waters, AH White, Aust J Chem 1996, 49, 27.
         | Crossref | GoogleScholarGoogle Scholar |

[33]  Schilling L-H, Reinsch H, Stock N. Synthesis, Structure, and Selected Properties of Aluminum-, Gallium-, and Indium-Based Metal–Organic Frameworks. Wiley; 2016. pp. 105–135,
| Crossref |

[34]  T Schäfer, K Müller-Buschbaum, Z. Anorg. Allg Chem 2018, 644, 1791.
         | Crossref | GoogleScholarGoogle Scholar |

[35]  NY Gugin, A Virovets, E Peresypkina, EI Davydova, AY Timoshkin, CrystEngComm 2020, 22, 4531.
         | Crossref | GoogleScholarGoogle Scholar |

[36]  J Heine, M Hołyńska, M Reuter, B Haas, S Chatterjee, M Koch, KI Gries, K Volz, S Dehnen, Cryst Growth Des 2013, 13, 1252.
         | Crossref | GoogleScholarGoogle Scholar |

[37]  T Schäfer, AE Sedykh, J Becker, K Müller-Buschbaum, Z Anorg Allg Chem 2020, 646, 1555.
         | Crossref | GoogleScholarGoogle Scholar |

[38]  TC Schäfer, J Becker, AE Sedykh, K Müller-Buschbaum, Z Anorg Allg Chem 2021, 647, 1227.
         | Crossref | GoogleScholarGoogle Scholar |

[39]  SP Petrosyants, Russ J Inorg Chem 2013, 58, 1605.
         | Crossref | GoogleScholarGoogle Scholar |

[40]  SP Petrosyants, AB Ilyukhin, Russ J Inorg Chem 2010, 55, 30.
         | Crossref | GoogleScholarGoogle Scholar |

[41]  SP Petrosyants, AB Ilyukhin, Russ J Inorg Chem 2011, 56, 2047.
         | Crossref | GoogleScholarGoogle Scholar |

[42]  TN Sevastianova, EI Davydova, IV Kazakov, AY Timoshkin, Russ Chem Bull 2015, 64, 2523.
         | Crossref | GoogleScholarGoogle Scholar |

[43]  TN Sevastianova, M Bodensteiner, AF Maulieva, EI Davydova, AV Virovets, EV Peresypkina, G Balázs, C Graßl, M Seidl, M Scheer, G Frenking, EA Berezovskaya, IV Kazakov, OV Khoroshilova, AY Timoshkin, Dalton Trans 2015, 44, 20648.
         | Crossref | GoogleScholarGoogle Scholar | 26564471PubMed |

[44]  CR Samanamú, AF Richards, Polyhedron 2007, 26, 923.
         | Crossref | GoogleScholarGoogle Scholar |

[45]  TN Sevastianova, M Bodensteiner, AS Lisovenko, EI Davydova, M Scheer, TV Susliakova, IS Krasnova, AY Timoshkin, Dalton Trans 2013, 42, 11589.
         | Crossref | GoogleScholarGoogle Scholar | 23824052PubMed |

[46]  CR Samanamú, PM Lococo, AF Richards, Inorg Chim Acta 2007, 360, 4037.
         | Crossref | GoogleScholarGoogle Scholar |

[47]  LM Engelhardt, PC Junk, CL Raston, BW Skelton, AH White, Dalton Trans 1996, 3297.
         | Crossref | GoogleScholarGoogle Scholar |

[48]  I Krossing, H Nöth, H Schwenk-Kircher, T Seifert, C Tacke, Eur J Inorg Chem 1998, 1998, 1925.
         | Crossref | GoogleScholarGoogle Scholar |

[49]  RJ Baker, AJ Davies, C Jones, M Kloth, J Organomet Chem 2002, 656, 203.
         | Crossref | GoogleScholarGoogle Scholar |

[50]  P Peter, H Karl, WB Jan, Z Naturforsch B 1982, 37, 1312.
         | Crossref | GoogleScholarGoogle Scholar |

[51]  RI Walton, Chem Soc Rev 2002, 31, 230.
         | Crossref | GoogleScholarGoogle Scholar | 12164069PubMed |

[52]  J Heine, T Wehner, R Bertermann, A Steffen, K Müller-Buschbaum, Inorg Chem 2014, 53, 7197.
         | Crossref | GoogleScholarGoogle Scholar | 24963536PubMed |

[53]  G Sheldrick, Acta Crystallogr, Sect A 2008, 64, 112.
         | Crossref | GoogleScholarGoogle Scholar | 18156677PubMed |

[54]  G Sheldrick, Acta Crystallogr, Sect C 2015, 71, 3.
         | Crossref | GoogleScholarGoogle Scholar |

[55]  G Sheldrick, Acta Crystallogr, Sect A 2015, 71, 3.
         | Crossref | GoogleScholarGoogle Scholar |

[56]  OV Dolomanov, LJ Bourhis, RJ Gildea, JAK Howard, H Puschmann, J Appl Crystallogr 2009, 42, 339.
         | Crossref | GoogleScholarGoogle Scholar |

[57]  W Pennington, J Appl Crystallogr 1999, 32, 1028.
         | Crossref | GoogleScholarGoogle Scholar |

[58]  A Coelho, J Appl Crystallogr 2018, 51, 210.
         | Crossref | GoogleScholarGoogle Scholar |