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RESEARCH ARTICLE
Contents Vol 75(9)

Coordination polymers based on aluminum and indium halides together with pyrazine†

Thomas C. Schäfer A , Jonathan Becker A , Dominik Heuler A , Marcel T. Seuffert A , Alexander E. Sedykh A and Klaus Müller-Buschbaum https://orcid.org/0000-0002-2857-8379 A B *
+ Author Affiliations
- Author Affiliations

A Institute of Inorganic and Analytical Chemistry, Justus-Liebig University Giessen, Heinrich-Buff-Ring 17, 35392 Giessen, Germany.

B Center for Materials Research (LaMa), Justus-Liebig University Giessen, Heinrich-Buff-Ring 16, 35392 Giessen, Germany.

* Correspondence to: kmbac@uni-giessen.de

Handling Editor: George Koutsantonis

Australian Journal of Chemistry 75(9) 676-683 https://doi.org/10.1071/CH21317
Submitted: 1 December 2021  Accepted: 3 February 2022   Published: 7 April 2022

© 2022 The Author(s) (or their employer(s)). Published by CSIRO Publishing.

Abstract

Four structurally closely related one-dimensional coordination polymers (CPs) have been synthesised, constituted by pyrazine (pyz) and the group 13 metal halides AlCl3, AlI3, InBr3, and InI3. Three CPs are isotypic: CH21317_IE1.gif, CH21317_IE2.gif, CH21317_IE3.gif. Alike CH21317_IE4.gif, they form linear chains. Hereby, each M3+ ion is trigonal-bipyramidally coordinated by three halido ligands and two N-atoms of two pyz serving as linear nodes with twofold connectivity (2-c). The CPs were characterised by SCXRD, PXRD, elemental-analysis, simultaneous DTA/TG and IR-spectroscopy. In addition, two complexes [(AlCl3)2(pyz)5] and [(InI3)2(pyz)] with octahedrally coordinated Al3+ and unprecedented tetrahedrally coordinated In3+ ions were structurally characterised by SCXRD.

Keywords: aluminum, bromide, chloride, coordination polymer, group 13 elements, indium, iodide, N-ligands, Pyrazine.


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