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RESEARCH ARTICLE
Contents Vol 73(12)

Vortex Fluidic Ethenolysis, Integrating a Rapid Quench of Ruthenium Olefin Metathesis Catalysts

Scott J. Pye A , Justin M. Chalker A B and Colin L. Raston https://orcid.org/0000-0001-6704-5105 A B
+ Author Affiliations
- Author Affiliations

A Flinders Institute for Nanoscale Science and Technology, College of Science and Engineering, Flinders University, Bedford Park, SA 5042, Australia.

B Corresponding authors. Email: justin.chalker@flinders.edu.au; colin.raston@flinders.edu.au

Australian Journal of Chemistry 73(12) 1138-1143 https://doi.org/10.1071/CH20005
Submitted: 6 January 2020  Accepted: 29 April 2020   Published: 26 June 2020

Abstract

Ruthenium-catalysed ethenolysis occurs in a vortex fluidic device (VFD) – a scalable, thin-film microfluidic continuous flow process. This process takes advantage of the efficient mass transfer of gaseous reagents into the dynamic thin film of liquid. Also reported is the rapid quenching of the ruthenium-based olefin metathesis catalyst by the addition of a saturated solution of N-acetyl-l-cysteine in MeCN, as a convenient alternative to previously reported quenching methods.


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