A Highly Sensitive Non-Enzymatic Sensor Based on a Cu/MnO2/g-C3N4-Modified Glassy Carbon Electrode for the Analysis of Hydrogen Peroxide Residues in Food Samples
Gaopeng Dai A , Jingwen Xie A , Cheng Li A and Suqin Liu A B
+ Author Affiliations
- Author Affiliations
A School of Chemical Engineering and Food Science, Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices, Hubei University of Arts and Science, Xiangyang 441053, China.
B Corresponding author. Email: liusuqin888@126.com
Australian Journal of Chemistry 70(10) 1118-1126 https://doi.org/10.1071/CH17072
Submitted: 7 February 2017 Accepted: 26 May 2017 Published: 20 June 2017
Abstract
A simple and highly sensitive method for the determination of hydrogen peroxide was developed by electrodepositing Cu and MnO2 onto a g-C3N4 coated glassy carbon electrode in a one-step procedure. The morphology of the fabricated electrode material was characterized by scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). The electrochemical properties were measured using cyclic voltammetry (CV) and chronoamperometry. The modified sensor exhibits high catalytic activity towards electrochemical oxidation of hydrogen peroxide in a neutral phosphate buffer solution. Within the concentration ranges of 0.01–20 mM and 20–400 mM, the fabricated sensor shows a good linear relationship with the oxidation peak current, the detection limit is 0.85 × 10−6 M. Furthermore, the sensor exhibits high selectivity, good stability, and reproducibility. We successfully applied the sensor to detect hydrogen peroxide residues in food samples with satisfactory results, providing a new approach for food security evaluation.
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