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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Putting David Craig’s Legacy to Work in Nanotechnology and Biotechnology*

Jeffrey R. Reimers
+ Author Affiliations
- Author Affiliations

International Centre for Quantum and Molecular Structures, College of Sciences, Shanghai University, Shanghai 200444, China, and School of Mathematical and Physical Sciences, The University of Technology Sydney, Sydney, NSW 2007, Australia. Email: jeffrey.reimers@uts.edu.au

Australian Journal of Chemistry 69(12) 1331-1359 https://doi.org/10.1071/CH16489
Submitted: 27 August 2016  Accepted: 7 October 2016   Published: 4 November 2016

Abstract

David Craig (1919–2015) left us with a lasting legacy concerning basic understanding of chemical spectroscopy and bonding. This is expressed in terms of some of the recent achievements of my own research career, with a focus on integration of Craig’s theories with those of Noel Hush to solve fundamental problems in photosynthesis, molecular electronics (particularly in regard to the molecules synthesized by Maxwell Crossley), and self-assembled monolayer structure and function. Reviewed in particular is the relation of Craig’s legacy to: the 50-year struggle to assign the visible absorption spectrum of arguably the world’s most significant chromophore, chlorophyll; general theories for chemical bonding and structure extending Hush’s adiabatic theory of electron-transfer processes; inelastic electron-tunnelling spectroscopy (IETS); chemical quantum entanglement and the Penrose–Hameroff model for quantum consciousness; synthetic design strategies for NMR quantum computing; Gibbs free-energy measurements and calculations for formation and polymorphism of organic self-assembled monolayers on graphite surfaces from organic solution; and understanding the basic chemical processes involved in the formation of gold surfaces and nanoparticles protected by sulfur-bound ligands, ligands whose form is that of Au0-thiyl rather than its commonly believed AuI-thiolate tautomer.


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