Charge Localisation in Heavy Alkali Metal Ion Complexes of 4,4′-Biphenyldicarboxylate*
Jack Harrowfield A C and Pierre Thuéry B
+ Author Affiliations
- Author Affiliations
A ISIS, Université de Strasbourg, 8 allée Gaspard Monge, 67083 Strasbourg, France.
B CEA, IRAMIS, CNRS UMR 3685 NIMBE, LCMCE, Bât. 125, 91191 Gif-sur-Yvette, France.
C Corresponding author. Email: harrowfield@unistra.fr
Australian Journal of Chemistry 69(5) 505-511 https://doi.org/10.1071/CH15691
Submitted: 30 October 2015 Accepted: 25 November 2015 Published: 17 December 2015
Abstract
Crystal structure determinations on the isomorphous RbI and CsI complexes of 4,4′-biphenyldicarboxylate have shown the carboxylate entities to be coordinated in an unusual fashion where both oxygen atoms are in a tetrahedral environment indicative of negative charge localisation on each. The metal ions also show a highly irregular form of six-coordination, while the biphenyl units are planar, seemingly as a result of attractive interactions between the ortho hydrogen atoms.
References
[1] P. Thuéry, J. Harrowfield, Inorg. Chem. 2015, 54, 8093.and references therein.| Crossref | GoogleScholarGoogle Scholar | 26241368PubMed |
[2] C. Gourlaouen, O. Parisel, H. Gérard, Dalton Trans. 2011, 40, 11282.and references therein.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXhtlejt7nI&md5=308fa644d89780f02d486ab3c1d6ab5aCAS | 21952712PubMed |
[3] S. K. Wolff, D. J. Grimwood, J. J. McKinnon, M. J. Turner, D. Jayatilaka, M. A. Spackman, CrystalExplorer 3.1 2012 (University of Western Australia: Perth).
[4] M. A. Spackman, D. Jayatilaka, CrystEngComm 2009, 11, 19.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1MXhsVCksg%3D%3D&md5=708a759aa83bb56c4f0f92b0ec7b4c19CAS |
[5] Y. H. Lee, A. Fuyuhiro, J. M. Harrowfield, Y. Kim, A. N. Sobolev, S. Hayami, Eur. J. Inorg. Chem. 2013, 5862.and references therein.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3sXhvVarurrM&md5=bd64f72775addfe93ba447de65b47e5eCAS |
[6] C. Oldham, in Comprehensive Coordination Chemistry (Eds G. Wilkinson, R. D. Gillard, J. A. McCleverty) 1987, Vol. 2, Ch. 15.6, pp. 435–459 (Pergamon Press: Oxford).
[7] A. Ouchi, Y. Suzuki, Y. Ohki, Y. Koizumi, Coord. Chem. Rev. 1988, 92, 29.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaL1MXoslaltw%3D%3D&md5=f9f28c2efe5ad0693496036888e5584bCAS |
[8] D. J. Tranchemontagne, J. L. Mendoza-Cortés, M. O’Keeffe, O. M. Yaghi, Chem. Soc. Rev. 2009, 38, 1257.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1MXkvValsr8%3D&md5=773909b294d6d37915af89b6f99a0a1dCAS | 19384437PubMed |
[9] R. Wang, Z. Zheng, in Rare Earth Coordination Chemistry: Fundamentals and Applications (Ed. C. Huang) 2010, Ch. 3, pp. 91–136 (John Wiley and Sons: New York, NY).
[10] M. L. Hu, A. Morsali, L. Aboutorabi, Coord. Chem. Rev. 2011, 255, 2821.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXhtlygsb%2FE&md5=79418358976d93536cbf1f5a86905f0dCAS |
[11] L.-N. Jin, Q. Liu, W.-Y. Sun, CrystEngComm 2014, 16, 3816.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC2cXmtFSnu7w%3D&md5=ee43f269d2e752290bd7288fc9806022CAS |
[12] Y. Rachuri, B. Parmar, K. K. Bisht, E. Suresh, Inorg. Chem. Front. 2015, 2, 228.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC2MXnvVajsw%3D%3D&md5=66d8b2c23d1ad3f2142c6e5926e37457CAS |
[13] J.-W. Zhang, X.-M. Kan, X.-L. Li, J. Luan, X.-L. Wang, CrystEngComm 2015, 17, 3887.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC2MXmsVCgs7g%3D&md5=fac07d26a3c9d7d99445b582893c14d0CAS |
[14] K. A. Mani, V. Viswanathan, S. Narasimhan, D. Velmurugan, Acta Crystallogr. Sect. E: Struct. Rep. Online 2014, 70, o1060.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC2cXhsVyjtLzF&md5=ecc2ea864d59da6090fc09d507d8a585CAS |
[15] G. A. Sim, J. M. Robertson, T. H. Goodwin, Acta Crystallogr. 1955, 8, 157.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaG2MXjvVagtw%3D%3D&md5=ec9a4a3422eb5645ccb603449c03ab4bCAS |
[16] H.-H. Wang, L.-N. Jia, L. Hou, W.-J. Shi, Z. Zhu, Y.-Y. Wang, Inorg. Chem. 2015, 54, 1841.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC2MXhvVOitL8%3D&md5=84ed21cddb115175021d1a0c67ab2e2bCAS | 25633091PubMed |
[17] V. A. Efremov, N. O. Endeladze, V. M. Agre, V. K. Trunov, Zh. Strukt. Khim. 1986, 27, 177.
| 1:CAS:528:DyaL28Xlt1Cks7c%3D&md5=360ed67706312dd60b67151d6f5abd64CAS |
[18] T. Behrsing, G. B. Deacon, P. C. Junk, B. W. Skelton, A. N. Sobolev, A. H. White, Z. Anorg. Allg. Chem. 2013, 639, 41.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC38XhvVCht7rL&md5=9a49198231bddc2b2609eb8e6983a652CAS |
[19] M.-A. Dang, Z.-F. Li, Y. Liu, G. Li, Aust. J. Chem. 2015, 68, 956.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC2MXpslGhur0%3D&md5=634b3ef6ee1836d7cea0bc8675198ab6CAS |
[20] X. Zhang, L. Fan, Z. Sun, W. Zhang, W. Fan, L. Sun, X. Zhao, CrystEngComm 2013, 15, 4910.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3sXot1equr8%3D&md5=2ff499ec85c6d981200ede693f1f02c9CAS |
[21] See Section 9.2.4.2 in: N. G. Connelly, T. Damhus, R. M. Hartshorn, A. T. Hutton, Nomenclature of Inorganic Chemistry 2005 (RSC Publishing: Cambridge).
[22] X. Zhang, Y.-Y. Huang, M.-J. Zhang, J. Zhang, Y.-G. Yao, Cryst. Growth Des. 2012, 12, 3231.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC38XmslKjsr0%3D&md5=78b4ac7c8f9fba91ed8e770b9eee3ccbCAS |
[23] F. J. Martinez-Casado, M. Ramos-Riesco, M. I. Redondo, D. Choquesillo-Lazaret, S. Lopes-Andrés, J. A. Rodriguez-Cheda, Cryst. Growth Des. 2011, 11, 1021.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXivFCntbY%3D&md5=53b301d4b547a9f649370b91b231aa64CAS |
[24] A. E. Martell, R. D. Hancock, R. D. Motekaitis, Coord. Chem. Rev. 1994, 133, 39.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2cXlvVylsb8%3D&md5=4fd4e8953a4f3203cd17aa3d1a20af01CAS |
[25] A. Lossin, G. Meyer, Z. Anorg. Allg. Chem. 1993, 619, 1462.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK3sXmvVakt78%3D&md5=3799f7334300fed061778d126960e010CAS |
[26] S. Burnet, A. K. Hall, J. M. Harrowfield, G. A. Koutsantonis, V. Sanford, D. Sauter, B. W. Skelton, A. H. White, Supramol. Chem. 2003, 15, 291.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3sXlsVCksb4%3D&md5=6a9810147f42e20754b77c9d795ebab2CAS |
[27] R. W. W. Hooft, COLLECT 1998 (Nonius BV: Delft, The Netherlands).
[28] Z. Otwinowski, W. Minor, Methods Enzymol. 1997, 276, 307.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2sXivFehsbw%3D&md5=f96199ba54b699fd2edf88385cf30f88CAS |
[29] G. M. Sheldrick, Acta Crystallogr. Sect. A: Found. Adv. 2015, 71, 3.
| Crossref | GoogleScholarGoogle Scholar |
[30] (a) G. M. Sheldrick, Acta Crystallogr. Sect. A: Found. Adv. 2008, 64, 112.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXhsVGhurzO&md5=59f548f8f29686b585f885edea91b42eCAS |
(b) G. M. Sheldrick, Acta Crystallogr. Sect. C: Struct. Chem. 2015, 71, 3.
| Crossref | GoogleScholarGoogle Scholar |
