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RESEARCH ARTICLE
Contents Vol 68(7)

Synthesis and Characterization of SmIII and EuIII Coordination Compounds of 3-(2-Pyridyl)-1-pyrazolyl Acetic Acid

Jian Hua Zou A , Qiao Liu A , Jia Fang Dong A , Meng Jie Cao A , Qian Qian Wu A , Qiu Yan Yue A , Qiao Yun Li A B and Gao Wen Yang A B
+ Author Affiliations
- Author Affiliations

A Department of Chemistry and Material Engineering, Jiangsu Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, 215500, China.

B Corresponding authors. Email: liqiaoyun61@126.com; ygwsx@126.com

Australian Journal of Chemistry 68(7) 1152-1159 https://doi.org/10.1071/CH14501
Submitted: 9 August 2014  Accepted: 11 December 2014   Published: 21 April 2015

Abstract

Two novel coordination compounds, namely, [Sm2(pypza)2(H2O)10]Cl4·H2O (1) and [Eu(pypza)(C2O4)] (2), where pypza = 3-(2-pyridyl)-1-pyrazolyl acetato, have been synthesized under hydrothermal conditions. These compounds were characterized by elemental analysis, infrared spectroscopy, and single-crystal X-ray diffraction. The X-ray diffraction analysis reveals that compound 1 displays double one-dimensional chains, whereas 2 shows a two-dimensional layer structure via the bridging pypza and oxalate (C2O42–) which may arise from the oxidation of hydroacetic acid through the decomposition and hydrolysis of Hpypza by means of the cleavage of the C–N bond between the carboxylate group and the pyrazolyl ring. Compounds 1 and 2 show three-dimensional networks by hydrogen bonding interactions. Furthermore, the luminescence properties of 1 and 2 have also been investigated at room temperature in the solid state.


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