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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Depsidone synthesis. V. The chemistry of psoromic acid: a reinvestigation

S Huneck and MV Sargent

Australian Journal of Chemistry 29(5) 1059 - 1067
Published: 1976

Abstract

The structure of the lichen depsidone psoromic acid (1) (4-formyl-3-hydroxy-8-methoxy-1,9-dimethyl-ll-oxo-11H-dibenzo[b,e][l,4]dioxepin-6-carboxylic acid) is confirmed by a combination of spectroscopic, degradative and synthetic experiments. Smiles rearrangements encountered in the degradation of psoromic acid are discussed.

https://doi.org/10.1071/CH9761059

© CSIRO 1976

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