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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Synthesis of polydepsipeptides with regularly repeating unit sequences

FHC Stewart

Australian Journal of Chemistry 22(6) 1291 - 1298
Published: 1969

Abstract

Sequential polydepsipeptides have been obtained by linear condensation of depsipeptide p-nitrophenyl ester active monomers. One of the products, poly-L-prolyl-L-alanylglycollic acid, is a depsipeptide analogue of a known polypeptide model for collagen. Synthesis of the active monomers involved the use of the pentamethylbenzyl carboxyl- protecting group, and the formation of depsipeptide ester bonds by accelerated active ester coupling.

https://doi.org/10.1071/CH9691291

© CSIRO 1969

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