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RESEARCH ARTICLE
Contents Vol 73(6)

Structures of 1 : 1 Mononuclear Adducts of Zinc(ii) Halides, ZnX2 (X = Cl, Br, I) and of New Hydrates of 1 : 1 Adducts of Zinc(ii) Nitrate and Sulfate with Aromatic N,N′′-Bidentate Base Derivatives of Pyridine (bpy, phen)

Graham A. Bowmaker A E , Yang Kim B C , Brian W. Skelton B , Alexandre N. Sobolev B and Allan H. White B D
+ Author Affiliations
- Author Affiliations

A School of Chemical Sciences, University of Auckland, Private Bag 92019, Auckland 1142, New Zealand.

B School of Molecular Sciences, Chemistry M310, The University of Western Australia, Perth, WA 6009, Australia.

C International Research Organization for Advanced Science and Technology (IROAST), Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan.

D Deceased.

E Corresponding author. Email: ga.bowmaker@auckland.ac.nz

Australian Journal of Chemistry 73(6) 511-519 https://doi.org/10.1071/CH19365
Submitted: 1 August 2019  Accepted: 17 September 2019   Published: 25 November 2019

Abstract

Single crystal X-ray structure determinations have been executed for several title compounds of the mononuclear form [LMX2], namely [(bpy)ZnX2], X = Cl, Br; [(phen)ZnX2], X = Cl, Br, I (bpy = 2,2′-bipyridine; phen = 1,10-phenanthroline). Also reported are the crystal structures of ZnSO4/bpy/H2O (1 : 1 : 5) (≡ [(bpy)Zn(OH2)4](SO4)·H2O) and Zn(NO3)2/bpy/H2O (1 : 1 : 3) (≡ [(bpy)Zn(OH2)3(ONO2)](NO3)). The sulfate complex completes the array [LM(OH2)4]2+, L = bpy, phen, M = Zn, Cd, while the nitrate is the first nitrate example for [LM(OH2)3(OX)](+) (OX = ONO2, OSO3). In all examples of the sulfate and nitrate forms here and previously defined, the metal atoms are six-coordinate, with any anionic donors lying in axial coordination sites (i.e. M–O (quasi-) normal to the LM plane). The structures of [LHg(SCN)2] (L = phen, tpy) (tpy = 2,2′:6′,2′-terpyridine), [(tpy)(CdBr2], and [Zn(tpy)2](NO3)2·2H2O are also recorded.


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