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RESEARCH ARTICLE
Contents Vol 72(10)

A Series of Early Lanthanide Chloranilate Frameworks with a Square Grid Topology

Carol Hua https://orcid.org/0000-0002-4207-9963 A B C , Hui Min Tay A , Qilin He B and T. David Harris B C
+ Author Affiliations
- Author Affiliations

A School of Chemistry, The University of Melbourne, Parkville, Vic. 3010, Australia.

B Department of Chemistry, Northwestern University, Evanston, IL 60208, USA.

C Corresponding authors. Email: carol.hua@unimelb.edu.au; dharris@northwestern.edu

Australian Journal of Chemistry 72(10) 778-785 https://doi.org/10.1071/CH19193
Submitted: 30 April 2019  Accepted: 7 June 2019   Published: 4 July 2019

Abstract

A series of lanthanide chloranilate frameworks containing a (4,4)-net with LaIII, CeIII, NdIII, SmIII, and EuIII have been synthesised and structurally characterised. Two structure types of square grids were obtained for these frameworks. Type 1 consists of the formula (Et4N)[Ln(can)2(H2O)] (Ln = LaIII, CeIII, NdIII; H2can = chloranilic acid) and crystallised in the tetragonal space group I4/m, featuring a nine-coordinate lanthanide ion with a coordinated water molecule and four chloranilate ligands. Type 2, (Et4N)[Ln(can)2] (SmIII and EuIII) crystallised in the I4/mcm space group, and contains an eight-coordinate lanthanide ion without a coordinated water molecule. A single-crystal-to-single-crystal transformation was carried out for (Et4N)[Nd(can)2(H2O)] on removal of the coordinated aqua ligand.


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