A Novel Eco-Friendly Scale and Corrosion Inhibitor Modified by β-Cyclodextrin

Mingjin Tang; Jianbo Li; Zhengrong Ye; Zimin Kou; Luoping Fu

doi:10.1071/CH16720

RESEARCH ARTICLE

Previous Next Contents Vol 70(8)

A Novel Eco-Friendly Scale and Corrosion Inhibitor Modified by β-Cyclodextrin

Mingjin Tang ^A ^C , Jianbo Li ^A ^C , Zhengrong Ye ^B , Zimin Kou ^A and Luoping Fu ^A

+ Author Affiliations

- Author Affiliations

^A College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China.

^B Research Institute of Petroleum Exploration and Development, Beijing 100083, China.

^C Corresponding authors. Email: tangmingjin@outlook.com; ljb0418@163.com

Australian Journal of Chemistry 70(8) 933-942 https://doi.org/10.1071/CH16720
Submitted: 17 December 2016 Accepted: 4 April 2017 Published: 23 May 2017

Abstract

A polymer, β-MEA, was synthesised from β-cyclodextrin (β-CD), 3-chloro-2-methylpropene (MAC), epoxysuccinic acid (ESA), and 2-acrylamido-2-methyl propane sulfonic acid (AMPS) with a (NH₄)₂S₂O₈-NaHSO₃ redox initiator system by aqueous solution radical polymerisation. β-MEA was characterised by means of IR spectroscopy, time-of-flight mass spectrometry, gel permeation chromatography, and thermogravimetric analysis. Its structure, molecular weight, thermal stability, scale and corrosion inhibition performance and mechanism were investigated. The results verified that β-MEA achieves a better scale inhibition efficiency for BaSO₄ compared with poly(aspartic acid) (PASP) (100 % cf. 94.9 % at a concentration of 20 mg L⁻¹) and a better corrosion inhibition efficiency of N80 carbon steel in saline water compared with PESA (91.2 % cf. 79.7 % at a concentration of 1 g L⁻¹). The BaSO₄ was characterised by scanning electron microscopy (SEM) and X-ray diffraction to investigate the crystal morphology of the scale. Primary research on the mechanism for corrosion inhibition was carried by SEM-chemical analysis.

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A Novel Eco-Friendly Scale and Corrosion Inhibitor Modified by β-Cyclodextrin

Abstract

References

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