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RESEARCH ARTICLE
Contents Vol 70(5)

New Heterodinuclear Zn/Ln (Ln = Gd, Tb, Er, Yb) Complexes of Hexadentate N,N′-Bis(3-alkoxy-2-hydroxybenzyl)cyclohexane-1,2-diamines: Synthesis and Structure*

Norman Kelly A , Kathleen Schnaars A , Kerstin Gloe A , Thomas Doert A , Jan J. Weigand A B and Karsten Gloe A B
+ Author Affiliations
- Author Affiliations

A Department of Chemistry and Food Chemistry, TU Dresden, D-01062 Dresden, Germany.

B Corresponding authors. Email: jan.weigand@tu-dresden.de; karsten.gloe@chemie.tu-dresden.de

Australian Journal of Chemistry 70(5) 601-607 https://doi.org/10.1071/CH16716
Submitted: 15 December 2016  Accepted: 24 January 2017   Published: 20 February 2017

Abstract

Two N,N′-bis(3-alkoxy-2-hydroxybenzyl)cyclohexane-1,2-diamine proligands, H2L1 (R = OCH3) and H2L2 (R = OC2H5), and five heterodinuclear ZnII/LnIII complexes, [Zn(L)(µ-CH3COO)Ln(NO3)2], containing [L1]2– and Gd3+, Tb3+, Er3+, or Yb3+ and [L2]2– and Yb3+ have been synthesised and structurally characterised. The complexes are isostructural and crystallise in the P21/n monoclinic space group. Zinc(ii) is coordinated by the inner N2O2 donor set of the ligand and an oxygen of the bridging acetate anion; the lanthanide(iii) ions possess an O9 coordination environment involving the interaction with the ligand’s outer O4 donor set, two bidentate nitrate ions, and the bridging acetate.


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