Synthesis of a Novel Dibenzylamide Derivative of p-tert-Octylcalix[4]arene and its Extraction Properties Towards Noble Metal Ions*
Jee Young Kim A , Yoga Priastomo A , Shintaro Morisada A , Hidetaka Kawakita A , Keisuke Ohto A C and Yang Kim B
+ Author Affiliations
- Author Affiliations
A Department of Chemistry and Applied Chemistry, Saga University, 1-Honjo, Saga 840-8502, Japan.
B Department of Chemistry and Advanced Materials, Kosin University, 194 Wachi-Ro, Yeongdo-gu, Busan 606-701, South Korea.
C Corresponding author. Email: ohtok@cc.saga-u.ac.jp
Australian Journal of Chemistry 70(5) 450-455 https://doi.org/10.1071/CH16180
Submitted: 23 March 2016 Accepted: 17 July 2016 Published: 22 August 2016
Abstract
A N,N-dibenzylacetoamide derivative of p-tert-octylcalix[4]arene was synthesised and its solvent extraction of precious metals in nitric acid media was investigated for determining the effects of extractant concentration and contact time as well as nitric acid concentration in comparison with a N,N-diethylacetoamide derivative. The extraction properties with both derivatives exhibited a slight difference. The extraction reaction of divalent palladium with both derivatives is discussed by slope analysis. The stripping behaviour of the extractant loaded with silver and palladium is also described using various stripping solutions.
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