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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Interaction between Remote Chiral Centres: A Pseudoracemic Example*,**

Paul V. Bernhardt A , Raymond M. Carman A B and Tri T. Le A
+ Author Affiliations
- Author Affiliations

A School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, Qld 4072, Australia.

B Corresponding author. Email: carman@uq.edu.au

Australian Journal of Chemistry 68(4) 648-651 https://doi.org/10.1071/CH14597
Submitted: 30 September 2014  Accepted: 3 November 2014   Published: 5 January 2015

Abstract

High resolution 13C NMR, supported by X-ray crystallography, shows the true nature of the trichloro derivative from manool or sclareol as a mixture of diastereomers comprising 70 % 13R and 30 % 13S isomers.


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