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RESEARCH ARTICLE
Contents Vol 67(3)

Reactions of Adamantanethione with Ketenes: Formation of a 1,3,5-Dioxathiane

Nicholas Drinnan A and Curt Wentrup A B
+ Author Affiliations
- Author Affiliations

A School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, Qld 4072, Australia.

B Corresponding author. Email: wentrup@uq.edu.au

Australian Journal of Chemistry 67(3) 525-527 https://doi.org/10.1071/CH13449
Submitted: 28 August 2013  Accepted: 17 September 2013   Published: 1 October 2013

Abstract

The reaction between adamantanethione 1 and diphenylketene 9 yields 2,4-bis(diphenylmethylidene)-1,3,5-dioxathiane 14 via ketene–thione zwitterions. This is the first example of the formation of a 1,3,5-dioxathiane in a ketene reaction.


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