Heterotopic As,S,P and As,S,As Ligands: Synthesis and Theoretical Studies
Imola Sárosi A B , Menyhárt B. Sárosi A B , Peter Lönnecke A , Luminiţa Silaghi-Dumitrescu B C and Evamarie Hey-Hawkins A C
+ Author Affiliations
- Author Affiliations
A Universität Leipzig, Institut für Anorganische Chemie, Johannisallee 29, D-04103 Leipzig, Germany.
B Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Kogalniceanu 1, RO-400084 Cluj-Napoca, Romania.
C Corresponding author. Email: hey@uni-leipzig.de
Australian Journal of Chemistry 66(10) 1246-1252 https://doi.org/10.1071/CH13262
Submitted: 20 May 2013 Accepted: 11 June 2013 Published: 24 July 2013
Abstract
The heterotopic As,S,P ligands 1-AsPh2-2-StBu-3-PPh2-C6H3 (2) and 1-AsPh2-2-SH-3-PPh2-C6H3 (4) and dinucleating As,S,As ligand 1,3-(AsPh2)2-2-StBu-C6H3 (3) have been synthesized and characterized. The structural motif of these compounds suggests great potential for their use as monodentate, bidentate chelating, bidentate bridging, and tridentate ligands.
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