Mono, Di and Trifunctional Cyclic Organic Peroxides: The Effect of Substituents and Ring Size on their Thermolysis in 1,4-dioxan
Rosa Nesprias A B C , Gladys Eyler B and Adriana Cañizo B
+ Author Affiliations
- Author Affiliations
A Department of Science Basic, Agronomy Faculty, National University of Center of The Buenos Aires Province (UNCPBA), Italy Republic 780, (PC: 7300), Azul, Buenos Aires, Argentina.
B Department of Chemistry Engineering, Engineering Faculty, National University of the Center of the Buenos Aires Province (UNCPBA), del Valle Avenue 5737, (B7400JWI) Olavarría, Buenos Aires, Argentina.
C Corresponding author. Email: knespria@faa.unicen.edu.ar
Australian Journal of Chemistry 66(9) 1080-1087 https://doi.org/10.1071/CH13171
Submitted: 18 April 2013 Accepted: 20 May 2013 Published: 15 July 2013
Abstract
The thermal decomposition reaction of cyclic organic peroxides was studied in 1,4-dioxan at initial concentrations between ~10–4 and 10–2 mol L–1 and at a temperature interval between 100 and 170°C, according to the thermal stability of each compound. The kinetic behaviour observed in all systems studied follows a pseudo first order kinetic law up to at least ~86 % of peroxide conversion. An important substituent effect is operative on the rate constant values and consequently on the activation parameters of the thermal decomposition reaction. The application of different treatments (compensation affect or a statistical treatment) on the kinetic data shows the existence of two sets of cyclic peroxides with comparable kinetic behaviour. Different peroxide–solvent interaction mechanisms can be considered within each series.
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