New Elements on the Behaviour of a Bissulfinylmethyl Radical*
Rocio Martinez Mallorquin A , Guillaume Vincent A , Etienne Derat A , Max Malacria A , Jean-Philippe Goddard A B and Louis Fensterbank A B
+ Author Affiliations
- Author Affiliations
A Institut Parisien de Chimie Moléculaire (UMR CNRS 7201) – FR2769 UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris, France.
B Corresponding authors. Email: jean-philippe.goddard@upmc.fr; louis.fensterbank@upmc.fr
Australian Journal of Chemistry 66(3) 346-353 https://doi.org/10.1071/CH12545
Submitted: 13 December 2012 Accepted: 1 February 2013 Published: 7 March 2013
Abstract
In this article, we have studied the generation of a bissulfinylmethyl radical from the corresponding TEMPO and phenylselenyl bissulfoxide precursors. No univocal formation of the bissulfinylmethyl radical has been observed. Instead, complex mixtures have been obtained in thermal or photochemical conditions, showing prominent C–S homolytic bond cleavage.
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